An Efficient Synthesis of Chiral Alcohols via Catalytic Hydrogenation of Esters

被引：1
|
作者：
Yasunori Ino
Wataru Kuriyama
Osamu Ogata
Takaji Matsumoto
机构：
[1] Takasago International Corporation,Corporate Research & Development Division
来源：
Topics in Catalysis | 2010年 / 53卷
关键词：
Ester; Hydrogenation; Homogeneous; Ruthenium; Catalyst; Chiral; Alcohol; Amino alcohol; Diol;
D O I：
暂无
中图分类号：
学科分类号：
摘要：
A ruthenium complex was found to catalyze the hydrogenation of chiral esters without the loss of their optical purities under mild and neutral conditions. This method can avoid a violent quench step and an extraction step which accompany conventional reduction using metal hydride reagents such as sodium borohydride and lithium aluminum hydride.
引用
收藏
页码：1019 / 1024
页数：5
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