Synthetic, spectral and solution studies on imidazolate-bridged copper(II)-copper(II) and copper(II)-zinc(II) complexes

被引：0

作者：

Kumar S. ^{[1
]}

Patel R.N. ^{[1
]}

Khadikar P.V. ^{[1
]}

Pandeya K.B. ^{[1
,2
]}

机构：

[1] Department of Chemistry, APS University

[2] CSJM University

来源：

Journal of Chemical Sciences | 2001年 / 113卷 / 1期

关键词：

2-Ethylimidazolate-bridged; Anti-ferromagnetic interactions; Homo/hetero-binuclear complexes;

D O I：

10.1007/BF02708548

中图分类号：

学科分类号：

摘要：

Synthesis, spectral and solution studies on 2-ethyl imidazolate-bridged (2-EtIm) homo-binuclear copper(II)-copper(II) and hetero-binuclear copper(II)-zinc(II) homologue are described. Magnetic moment values of homo-binuclear complexes indicate that the imidazolate group can mediate antiferromagnetic interactions. Optical spectra of hetero-binuclear complex at varying pH values suggest that the imidazolate-bridged complex is stable over the pH-range 7.15-10.0.

引用

页码：21 / 27

页数：6

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