Synthetic, spectral and solution studies on imidazolate-bridged copper(II)-copper(II) and copper(II)-zinc(II) complexes

被引：0
|
作者：
Kumar S. [1 ]
Patel R.N. [1 ]
Khadikar P.V. [1 ]
Pandeya K.B. [1 ,2 ]
机构：
[1] Department of Chemistry, APS University
[2] CSJM University
来源：
Journal of Chemical Sciences | 2001年 / 113卷 / 1期
关键词：
2-Ethylimidazolate-bridged; Anti-ferromagnetic interactions; Homo/hetero-binuclear complexes;
D O I：
10.1007/BF02708548
中图分类号：
学科分类号：
摘要：
Synthesis, spectral and solution studies on 2-ethyl imidazolate-bridged (2-EtIm) homo-binuclear copper(II)-copper(II) and hetero-binuclear copper(II)-zinc(II) homologue are described. Magnetic moment values of homo-binuclear complexes indicate that the imidazolate group can mediate antiferromagnetic interactions. Optical spectra of hetero-binuclear complex at varying pH values suggest that the imidazolate-bridged complex is stable over the pH-range 7.15-10.0.
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页码：21 / 27
页数：6
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