Hydrogenation of furfuryl alcohol to tetrahydrofurfuryl alcohol on NiB/SiO2 amorphous alloy catalyst

被引：14
作者：
Yun Song
Wei Li
Minghui Zhang
Keyi Tao
机构：
[1] Nankai University,Institute of New Catalytic Material Science, College of Chemistry
来源：
Frontiers of Chemical Engineering in China | 2007年 / 1卷 / 2期
关键词：
amorphous alloy; NiB/SiO; hydrogenation; furfuryl alcohol (FA); tetrahydrofurfuryl alcohol (THFA);
D O I：
10.1007/s11705-007-0028-2
中图分类号：
学科分类号：
摘要：
NiB/SiO2 amorphous alloy catalyst was prepared by power electroless plating method and characterized by induction coupled plasma (ICP), Brunauer-Emmett-Teller method (BET), transmission electron microscope (TEM) and X-ray diffraction (XRD) techniques. The catalytic performance of NiB/SiO2 was investigated for the hydrogenation of furfuryl alcohol (FA) to tetrahydrofurfuryl alcohol (THFA). The effects of operational conditions, such as reaction temperature, pressure, and stirring rate were carefully studied. The proper conditions were determined as the following: pressure 2.0 MPa, temperature 120°C and stirring rate 550 r/min. A typical result with FA conversion of 99% and THFA selectivity of 100% was obtained under such conditions, which was close to that over Raney Ni.
引用
收藏
页码：151 / 154
页数：3
相关论文
共 47 条
[1]  
Zhao H. J.(2001)Study of the catalysts for hydrogenation of furfuryl alcohol to tetrahydrofurfuryl alcohol Fine Chem 18 332-334
[2]  
Liu C. G.(2003)Preparation of tetrahydrofurfuryl alcohol using hydrogenation of furfuryl alcohol catalyzed by raney nickel catalyst J Univ Petrol 27 91-94
[3]  
Zhao H. J.(2005)Experimental study for liquid phase hydrogenation of furfuryl alcohol to tetrahydrofurfuryl alcohol on a Ni-supported catalyst J Beijing Univ Chem Technol 32 39-42
[4]  
Xing J. X.(2005)Research progress of amorphous alloy catalyst Contemporary Chem Indus 34 210-213
[5]  
Liu C. G.(2003)The latest research progress of amorphous alloy catalysts Chem Propell Polym Mater 1 44-47
[6]  
Xiao N.(2000)Micro-Raman spectroscopy of Pd-B/SiO Raman Spectrosc 31 1051-1055
[7]  
Chen X. C.(2004) amorphous alloy catalyst Chinese J App Chem 21 231-234
[8]  
Yan Y. J.(2004)Preparation of amorphous NiB/NaBETA alloy catalyst by electroless plating and the hydrogenation of sulfolene Chinese Chem Lett 15 1357-1360
[9]  
Liu S. W.(2003)Effect of TiO J Mole Catal 17 450-455
[10]  
Liu Q. F.(2004) support on the composition, morphology and catalytic property of the NiB amorphous alloy catalyst Acta Scientiarum Naturalium Universitatis Nankaiensis 37 1-6
12345