Nonlinear optical properties of new synthesized conjugated organic molecules based on pyrimidine and oxazepine

被引:6
作者
Sofiani Z. [1 ]
Khannyra S. [1 ]
Boucetta A. [1 ]
ElJouad M. [2 ]
Bouchouit K. [3 ]
Serrar H. [4 ]
Boukhris S. [4 ]
Souizi A. [4 ]
Migalska-Zalas A. [5 ]
机构
[1] LOPCM Laboratory, Faculty of Science, Ibn Tofail University, Kenitra
[2] Ecole Nationale des Sciences Appliquées (ENSAJ), Université Chouaïb Doukkali, El Jadida
[3] Chemistry Department, Faculty of Exact Sciences and Informatics, University of Jijel, Jijel
[4] Laboratoire de Synthese Organique, Organomtallique et Théorique, Faculty of Sciences, Ibn Tofail University, Kenitra
[5] Faculty of Mathematics and Natural Sciences, Institute of Physics, J. Dlugosz Academy of Czestochowa, Al. ArmiiKrajowej 13/15, Czestochowa
关键词
Conjugated organic molecules; Nonlinear optics; Second order hyperpolarizabilities; THG;
D O I
10.1007/s11082-016-0549-3
中图分类号
学科分类号
摘要
The third order nonlinear optical properties were reported for a new synthesized molecules based on triazepine and thianine, using the third harmonic generation (THG) technique. After synthesis, the powders were deposited on glass substrates using dip coating technique in order get thin films. These thin films were characterized, by different techniques, we mention the absorption and X-ray diffraction. The measurements of third order nonlinear optical susceptibilities were performed on these thin films, using the THG technique at 1064 nm. These investigations were completed by theoretical studies, using energy levels theory HOMO–LUMO and the second order hyperpolarizabilities (γ) results. Good agreement was obtained between the theoretical and experimental results. © 2016, Springer Science+Business Media New York.
引用
收藏
相关论文
共 35 条
[21]  
Khurana J.M., Vij K., Nickel nanoparticles as semiheterogeneous catalyst for one-pot, three-component synthesis of 2-amino-4H-pyrans and pyran annulated heterocyclic moieties, Synth. Commun., 43, 17, pp. 2294-2304, (2013)
[22]  
Khurana J.M., Nandand B., Saluja P., DBU: a highly efficient catalyst for one-pot synthesis of substituted 3,4-dihydropyrano[3,2-c]chromenes, dihydropyrano-[4,3-b] pyranes, 2-amino-4Hbenzo[h]chromenes and 2-amino-4H benzo[g]chromenes in aqueous medium, Tetrahedron, 66, 30, pp. 5637-5641, (2010)
[23]  
Kolev T., Kityk I.V., Ebothe J., Sahraoui B., Intrinsic hyperpolarizability of 3-dicyanomethylene-5,5-dimethyl-1-[2-(4-hydroxyphenyl)ethenyl]-cyclohexene nanocrystallites incorporated into the photopolymer matrices, Chem. Phys. Lett., 443, 4-6, pp. 309-312, (2007)
[24]  
Kraft A., Grimsdale A.C., Holmes A.B., Electroluminescent conjugated polymers—seeing polymers in a new light, Angew. Chem. Int. Ed., 37, pp. 402-428, (1998)
[25]  
Li L., Ge J., Wu H., Xu Q.H., Yao S.Q., Organelle-specific detection of phosphatase activities with two-photon fluorogenic probes in cells and tissues, J. Am. Chem. Soc., 134, pp. 12157-12167, (2012)
[26]  
Lian X.-Z., Huang Y., Li Y.-Q., Zheng W.-J., A green synthesis of tetrahydrobenzo[b]pyran derivatives through three-component condensation using N-methylimidazole as organocatalyst, Monatsh. Chem., 139, 2, pp. 129-131, (2008)
[27]  
Liu B., Hu X.L., Liu J., Zhao Y.D., Huang Z.L., Synthesis and photophysical properties of novel pyrimidine-based two-photon absorption chromophores, Tetrahedron Lett., 48, pp. 5958-5962, (2007)
[28]  
Migalska-Zalas A., Sofiani Z., Sahraoui B., Kityk I.V., Tkaczyk S., Yuvshenko V., Fillaut J.-L., Perruchon J., Muller T.J.J., χ<sup>(2)</sup> Grating in Ru Derivative Chromophores Incorporated within the PMMA Polymer Matrices, J. Phys. Chem. B, 108, 39, pp. 14942-14947, (2004)
[29]  
Sahraoui B., Nguyen Phu X., Salle M., Gorgues A., Electronic and nuclear contributions to the third-order nonlinear optical susceptibilities of new p-N, N′-dimethylaniline tetrathiafulvalene derivatives, Opt. Lett., 23, 23, pp. 1811-1813, (1998)
[30]  
Sheats J.R., Antoniadis H., Hueschen M., Leonard W., Miller J., Moon R., Roitman D., Stocking A., Effect of heat extraction by metal lines and two sided cooling on temperatures in organic light emitting diode based devices, Science, 273, pp. 884-888, (1996)