Nonlinear optical properties of new synthesized conjugated organic molecules based on pyrimidine and oxazepine

被引：6

作者：

Sofiani Z. ^{[1
]}

Khannyra S. ^{[1
]}

Boucetta A. ^{[1
]}

ElJouad M. ^{[2
]}

Bouchouit K. ^{[3
]}

Serrar H. ^{[4
]}

Boukhris S. ^{[4
]}

Souizi A. ^{[4
]}

Migalska-Zalas A. ^{[5
]}

机构：

[1] LOPCM Laboratory, Faculty of Science, Ibn Tofail University, Kenitra

[2] Ecole Nationale des Sciences Appliquées (ENSAJ), Université Chouaïb Doukkali, El Jadida

[3] Chemistry Department, Faculty of Exact Sciences and Informatics, University of Jijel, Jijel

[4] Laboratoire de Synthese Organique, Organomtallique et Théorique, Faculty of Sciences, Ibn Tofail University, Kenitra

[5] Faculty of Mathematics and Natural Sciences, Institute of Physics, J. Dlugosz Academy of Czestochowa, Al. ArmiiKrajowej 13/15, Czestochowa

来源：

Optical and Quantum Electronics | 2016年 / 48卷 / 05期

关键词：

Conjugated organic molecules; Nonlinear optics; Second order hyperpolarizabilities; THG;

D O I：

10.1007/s11082-016-0549-3

中图分类号：

学科分类号：

摘要：

The third order nonlinear optical properties were reported for a new synthesized molecules based on triazepine and thianine, using the third harmonic generation (THG) technique. After synthesis, the powders were deposited on glass substrates using dip coating technique in order get thin films. These thin films were characterized, by different techniques, we mention the absorption and X-ray diffraction. The measurements of third order nonlinear optical susceptibilities were performed on these thin films, using the THG technique at 1064 nm. These investigations were completed by theoretical studies, using energy levels theory HOMO–LUMO and the second order hyperpolarizabilities (γ) results. Good agreement was obtained between the theoretical and experimental results. © 2016, Springer Science+Business Media New York.

引用

共 35 条

[1]

Achelle S., Pyrimidine ring as building block for the synthesis of functionalized π-conjugated materials, Curr. Org. Synth., 9, pp. 163-187, (2012)

[2]

Achelle S., Baudequin C., Recent advances in pyrimidine derivatives as luminescent, photovoltaic and ono-linear optical materials, Targets Heterocycl. Syst., 17, pp. 1-34, (2013)

[3]

Achelle S., Kahlal S., Barsella A., Saillard J.-Y., Che X., Et al., Improvement of the quadratic non-linear optical properties of pyrimidine chromophores by N-methylation and tungsten pentacarbonyl complexation, Dyes Pigments, 113, pp. 562-570, (2015)

[4]

Ahluwalia V.K., Batla R., Khuranaand A., Kumar R., Synthesis of 1,3-diaryl-1,2,3,4-tetrahydro-7,7-diethyl-5-methyl-4-oxo-2-thioxo- 7H- pyrano(2,3-d)pyrimidines, Indian J. Chem., 29B, (1990)

[5]

Apostoluk A., Chapron D., Gadret G., Sahraoui B., Nunzi J.-M., Fiorini-Debuisschert C., Raimond P., Quasi-phase-matched gratings printed by all-optical poling in polymer films, Opt. Lett., 27, 22, pp. 2028-2030, (2002)

[6]

Azarifar D., Nejat-Yami R., Sameriand F., Akrami A., Ultrasonic-promoted one-pot synthesis of 4H-chromenes, pyrano[2,3- d]pyrimidines, and 4H-pyrano[2,3-c]pyrazoles, Lett. Org. Chem., 9, 6, pp. 435-439, (2012)

[7]

Becke D., Density-functional thermochemistry. III, the role of exact exchange, J. Chem. Phys., 98, pp. 5648-5652, (1993)

[8]

Bogaard M.P., Orr B.J., Buckingham A.D., MTP International Review of Science, vol. 2, pp. 149–194, (1975)

[9]

Brown R., Pomp A., Hart C.M., Deleeuw D.M., Logic gates made from polymer transistors and their use in ring oscillators, Science, 270, pp. 972-974, (1995)

[10]

Burroughes J.H., Bradley D.D.C., Brown A.R., Marks R.N., MacKay K., Friend R.H., Burn P.L., Holmes A.B., Light-emitting diodes based on conjugated polymers, Nature, 347, pp. 539-541, (1990)

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