Hydrothermal Synthesis and Characterization of a New Arsenic–Vanadium Compound with a β-[As8V14O42(SO4)]6− anion

被引：0
|
作者：
Guangpeng Zhou
Yan Xu
Chunyan Guo
Yuguo Liu
Xuefang Zheng
机构：
[1] Liaoning Normal University,Institute of Chemistry for Functionalized Materials, College of Chemistry and Chemical Engineering
[2] Dalian University,Liaoning Key Laboratory of Bio
来源：
Journal of Cluster Science | 2007年 / 18卷
关键词：
Arsenic–vanadium cluster; Crystal structure; Hydrothermal synthesis;
D O I：
暂无
中图分类号：
学科分类号：
摘要：
A new arsenic vanadium compound (NH4)2[N(CH3)4]4[β-As8V14O42(SO4)] 1 has been synthesized under hydrothermal conditions and characterized by single crystal X-ray diffraction, IR spectrum, elemental analysis and thermogravimetic (TG) analysis. Compound 1 crystallizes in monoclinic system with space group P2(1)/c, a = 11.4631(5) Å, b = 11.3539(5) Å, c = 24.6265(10) Å, β = 93.6620(10)°, V = 3198.6(2) Å3, Z = 2, R1 = 0.0421 and wR2 = 0.1044. The molecule structural analysis reveals that compound 1 has a β-[As8V14O42(SO4)]6− arsenic–vanadium cluster anion.
引用
收藏
页码：388 / 395
页数：7
相关论文
共 50 条
  • [1] Hydrothermal synthesis and characterization of a new arsenic-vanadium compound with a β-[As8V14O42(SO4)]6- anion
    Zhou, Guangpeng
    Xu, Yan
    Guo, Chunyan
    Liu, Yuguo
    Zheng, Xuefang
    JOURNAL OF CLUSTER SCIENCE, 2007, 18 (02) : 388 - 395
  • [2] Hydrothermal synthesis, characterization, and luminescence of two new arsenic-vanadium compounds with a -[As8V14O42(H2O)]4-anion
    Wang, Congling
    Zhou, Guangpeng
    Zhang, Zhibin
    Zhu, Dunru
    Xu, Yan
    JOURNAL OF COORDINATION CHEMISTRY, 2011, 64 (07) : 1198 - 1206
  • [3] Hydrothermal synthesis and crystal structure of (H2en)6[As8V14O42(SO4)]2•8H2O containing two [As8V14O42(SO4)]6- cluster anions
    Ding, H
    Zeng, QX
    Yang, GY
    Xu, JQ
    CHINESE JOURNAL OF STRUCTURAL CHEMISTRY, 2003, 22 (05) : 620 - 626
  • [4] Hydrothermal synthesis and characterization of two new arsenic-vanadate compounds with the same cluster anion [As8V14O42(H2O)]4-
    Zhou, Guangpeng
    Guo, Chunyan
    Liu, Wei
    Xu, Yan
    Zheng, Xuefang
    JOURNAL OF COORDINATION CHEMISTRY, 2008, 61 (02) : 202 - 210
  • [5] Hydrothermal synthesis and structure of a new arsenic-vanadium cluster:: [NH2(CH2CH2)2NH2]3 [As8V14O42(SO4)]•6.5H2O
    Zheng, ST
    Zhang, H
    Yang, GY
    JOURNAL OF MOLECULAR STRUCTURE, 2004, 705 (1-3) : 127 - 132
  • [6] Hydrothermal synthesis and characterization of (enH2)3.5[As8V14O42(PO4)]•2H2O
    Cui, XB
    Xu, JQ
    Li, Y
    Sun, YH
    Ye, L
    Guo-Yu, Y
    JOURNAL OF MOLECULAR STRUCTURE, 2003, 655 (01) : 207 - 213
  • [7] 含有两个簇阴离子[As8V14O42（SO4）]6-的金属-氧簇合物（H2en）6[As8V14O42（SO4）]28H2O的水热合成与晶体结构
    丁红
    曾庆新
    杨国昱
    徐吉庆
    结构化学, 2003, (05) : 621 - 627
  • [8] Hydorthermal synthesis and characterization of a new compound [Co(en)3]2•2H3O•[As8V14O42(HPO4)]•2H2O
    Li, YF
    Cui, W
    Wu, G
    Fang, QR
    Zhu, GS
    Li, BS
    Gao, FF
    Wang, CL
    Qiu, SL
    CHEMICAL JOURNAL OF CHINESE UNIVERSITIES-CHINESE, 2002, 23 (05): : 783 - 785
  • [9] Hydrothermal synthesis and structure characterization of a novel [Cu1(dpq)2]+ complex cations modified arsenic-vanadium polyoxometalate [Cu(dpq)2]4[As8V14O42(H2O)] • 2H2O
    Dong Bao-Xia
    Zhang Peng-Peng
    Peng Jun
    CHEMICAL JOURNAL OF CHINESE UNIVERSITIES-CHINESE, 2007, 28 (06): : 1018 - 1020
  • [10] Hydrothermal synthesis and characterization of (enH2)3.5[As8V14O42(PO4)]•2H2O (vol 655, pg 207, 2003)
    Cui, XB
    Xu, JQ
    Li, Y
    Sun, YH
    Ye, L
    Yang, GY
    JOURNAL OF MOLECULAR STRUCTURE, 2003, 657 (1-3) : 395 - +
12345