Physical Aging and Light Scattering of Low-Loss Poly(methyl methacrylate) Glass

被引:0
|
作者
Norihisa Tanio
Hisao Kato
Yasuhiro Koike
Harvey E Bair
Shiro Matsuoka
Lee L Blyler
机构
[1] Kanagawa Academy of Science and Technology,Faculty of Science and Technology
[2] Keio University,undefined
[3] Bell Laboratories,undefined
来源
Polymer Journal | 1998年 / 30卷
关键词
Physical Aging; Light Scattering Loss; Poly(methyl methacrylate); Glass Transition Temperature; Enthalpy Relaxation; Amorphous Polymer; Polymer Glass;
D O I
暂无
中图分类号
学科分类号
摘要
Isothermal aging has been carried out on low-loss poly(methyl methacrylate) (PMMA) glass at 18°C below the glass transition temperature (Tg). The effect of enthalpy relaxation on light scattering loss of PMMA glass which had no excess scattering was investigated by the use of differential scanning calorimeter (DSC) and light scattering measurement. The light scattering intensity of PMMA glass did not increase with increasing aging time. It is seen that the light scattering loss of glassy PMMA is not affected inherently by physical aging as a result of its approach to thermodynamic equilibrium at a temperature 18°C below its Tg.
引用
收藏
页码:56 / 59
页数:3
相关论文
共 50 条
  • [21] PHYSICAL AGING OF POLY(METHYL METHACRYLATE) FROM ENTHALPY RELAXATION MEASUREMENTS
    COWIE, JMG
    FERGUSON, R
    POLYMER, 1993, 34 (10) : 2135 - 2141
  • [22] EFFECT OF PHYSICAL AGING ON STRESS-RELAXATION OF POLY(METHYL METHACRYLATE)
    CIZMECIOGLU, M
    FEDORS, RF
    HONG, SD
    MOACANIN, J
    POLYMER ENGINEERING AND SCIENCE, 1981, 21 (14): : 940 - 942
  • [23] Physical aging in poly(ethylene oxide)/atactic-poly(methyl methacrylate) blends
    Vernel, J
    Rychwalski, RW
    Pelísek, V
    Sáha, P
    Schmidt, MK
    Maurer, FHJ
    THERMOCHIMICA ACTA, 1999, 342 (1-2) : 115 - 137
  • [24] STUDY ON GELS OF POLY(METHYL METHACRYLATE) STEREOCOMPLEX BY LIGHT-SCATTERING
    KATIME, IA
    QUINTANA, JR
    POLYMER JOURNAL, 1988, 20 (06) : 459 - 469
  • [25] LIGHT-SCATTERING STUDY ON THE STRUCTURE OF PURE POLY(METHYL METHACRYLATE)
    FUJIKI, M
    KAINO, T
    OIKAWA, S
    POLYMER JOURNAL, 1983, 15 (10) : 693 - 698
  • [26] ORIGIN OF EXCESS LIGHT-SCATTERING IN POLY(METHYL METHACRYLATE) GLASSES
    KOIKE, Y
    MATSUOKA, S
    BAIR, HE
    MACROMOLECULES, 1992, 25 (18) : 4807 - 4815
  • [27] ISOTHERMAL PHYSICAL AGING OF POLY(METHYL METHACRYLATE) - LOCALIZATION OF PERTURBATIONS IN THERMOMECHANICAL PROPERTIES
    VENDITTI, RA
    GILLHAM, JK
    JOURNAL OF APPLIED POLYMER SCIENCE, 1992, 45 (03) : 501 - 506
  • [28] Effect of physical aging on the gas transport properties of poly(methyl methacrylate) membranes
    Hu, Chien-Chieh
    Fu, Ywu-Jang
    Hsiao, Sheng-Wen
    Lee, Kueir-Rarn
    Lai, Juin-Yih
    JOURNAL OF MEMBRANE SCIENCE, 2007, 303 (1-2) : 29 - 36
  • [29] Physical Aging of Poly(methyl methacrylate) Brushes and Spin-Coated Films
    Srinivasan, Sneha
    Mcgaughey, Allyson L.
    Ren, Zhiyong Jason
    Zuo, Biao
    Priestley, Rodney D.
    JOURNAL OF PHYSICAL CHEMISTRY B, 2024, 128 (48): : 11999 - 12007