Dioxomolybdenum(VI) complexes containing 1-alkyl-2-ethyl-3-hydroxy-4-pyridin-4(1H)-ones

被引:0
作者
Nga Chiu Tam
Stephen P. Fletcher
Christopher M. Vogels
Stephen A. Westcott
Andreas Decken
机构
[1] Mount Allison University,Department of Chemistry
[2] University of New Brunswick,Department of Chemistry
来源
Transition Metal Chemistry | 2003年 / 28卷
关键词
Spectroscopy; Physical Chemistry; Ethyl; Inorganic Chemistry; General Formula;
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摘要
Dioxomolybdenum(VI) complexes derived from ethyl maltol (2-ethyl-3-hydroxy-4-pyrone) and 1-alkyl-2-ethyl-3-hydroxy-4-pyridin-4(1H)-ones have been prepared and characterized using physical methods including 1H- and 13C-n.m.r. spectroscopy, i.r., elemental analysis, and X-ray diffraction for the pyrone and 3-methylpyridine pyridinone derivatives. The octahedral complexes have the general formula cis-MoO2L2 where L = the deprotonated pyrone or pyridinone ligand.
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页码:103 / 109
页数:6
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