Dynamics of the swollen lamellar phase

被引:0
|
作者
T. Schilling
O. Theissen
G. Gompper
机构
[1] Institut für Festkörperforschung,
[2] Forschungszentrum Jülich,undefined
[3] D-52425 Jülich,undefined
[4] Germany,undefined
[5] Max-Planck-Institut für Kolloid- und Grenzflächenforschung,undefined
[6] Am Mühlenberg,undefined
[7] D-14476 Golm,undefined
[8] Germany,undefined
来源
关键词
PACS. 47.55.-t Nonhomogeneous flows - 68.10.-m Fluid surfaces and fluid-fluid interfaces - 82.70.-y Disperse systems;
D O I
暂无
中图分类号
学科分类号
摘要
We investigate the dynamical behavior of lamellar phases in ternary amphiphilic systems of water, oil and amphiphile. The interaction between the amphiphilic monolayers is described by the steric interaction due to thermal fluctuations for uncharged, and by electrostatic interactions for charged systems. The dynamics of the system is determined by the hydrodynamics of the fluid layers. The basic parameters of our model are the viscosities of the two solvents, the average thicknesses of the oil and water layers, and the bending rigidity. The model allows to consider different monolayer interactions across the oil and water layers. Relaxation rates are calculated for arbitrary wave vectors parallel and perpendicular to the average monolayer plane. We find that there is a quite complex crossover behavior from a \documentclass[12pt]{minimal} \usepackage{amsmath} \usepackage{wasysym} \usepackage{amsfonts} \usepackage{amssymb} \usepackage{amsbsy} \usepackage{mathrsfs} \usepackage{upgreek} \setlength{\oddsidemargin}{-69pt} \begin{document}\end{document} law for small parallel wave vectors to a \documentclass[12pt]{minimal} \usepackage{amsmath} \usepackage{wasysym} \usepackage{amsfonts} \usepackage{amssymb} \usepackage{amsbsy} \usepackage{mathrsfs} \usepackage{upgreek} \setlength{\oddsidemargin}{-69pt} \begin{document}\end{document} law for large \documentclass[12pt]{minimal} \usepackage{amsmath} \usepackage{wasysym} \usepackage{amsfonts} \usepackage{amssymb} \usepackage{amsbsy} \usepackage{mathrsfs} \usepackage{upgreek} \setlength{\oddsidemargin}{-69pt} \begin{document}\end{document}. We discuss the relevance of our result for the interpretation of dynamic light-scattering and neutron-spin-echo experiments for these systems.
引用
收藏
页码:103 / 114
页数:11
相关论文
共 50 条
  • [1] Dynamics of the swollen lamellar phase
    Schilling, T
    Theissen, O
    Gompper, G
    EUROPEAN PHYSICAL JOURNAL E, 2001, 4 (01): : 103 - 114
  • [2] Microrheology of a swollen lyotropic lamellar phase
    Kimura, Yasuyuki
    Mizuno, Daisuke
    MOLECULAR CRYSTALS AND LIQUID CRYSTALS, 2007, 478 (01) : 759 - 769
  • [3] DYNAMICS OF THE UNDULATION MODE IN SWOLLEN LAMELLAR PHASES
    MESSAGER, R
    BASSEREAU, P
    PORTE, G
    JOURNAL DE PHYSIQUE, 1990, 51 (12): : 1329 - 1340
  • [4] Flexibility of the membranes in a doped swollen lamellar phase
    Ponsinet, V
    Fabre, P
    JOURNAL OF PHYSICAL CHEMISTRY, 1996, 100 (12): : 5035 - 5038
  • [5] SURFACE FORCES IN A SWOLLEN LAMELLAR PHASE - UNDULATION FORCES
    PEREZ, E
    ABILLON, O
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 1989, 198 : 70 - COLL
  • [6] Effect of confinement on membrane undulation in a swollen lamellar phase
    Yamada, NL
    Takeda, T
    Kato, K
    Nagao, M
    Seto, H
    JOURNAL OF THE PHYSICAL SOCIETY OF JAPAN, 2005, 74 (03) : 875 - 877
  • [7] Photonic effect in a hyper-swollen lyotropic lamellar phase
    Kobayashi, Chikashi
    Yamamoto, Jun
    Takanishi, Yoichi
    JOURNAL OF APPLIED PHYSICS, 2012, 112 (01)
  • [8] Shear alignment of a swollen lamellar phase in a ternary polymer blend
    Krishnan, K
    Bates, FS
    Lodge, TP
    JOURNAL OF RHEOLOGY, 2005, 49 (06) : 1395 - 1408
  • [9] Interlayer distance dependence of thickness fluctuations in a swollen lamellar phase
    Nagao, Michihiro
    Chawang, Sukhum
    Hawa, Takumi
    SOFT MATTER, 2011, 7 (14) : 6598 - 6605
  • [10] EXPERIMENTAL-STUDY OF A LYOTROPIC LAMELLAR PHASE SWOLLEN WITH POLYMER-SOLUTIONS
    FICHEUX, MF
    BELLOCQ, AM
    NALLET, F
    JOURNAL DE PHYSIQUE II, 1995, 5 (06): : 823 - 834