Chemistry of unsaturated arenetricarbonylchromium compounds2. Synthesis of new isoxazolidine complexes by 1,3-dipolar cycloaddition reaction of nitrone (η6-arene)tricarbonylchromium derivatives with acrylonitrile

被引：0
|
作者：
N. Yu. Zarovkina
E. V. Sazonova
A. N. Artemov
G. K. Fukin
机构：
[1] N. I. Lobachevsky State University of Nizhny Novgorod,
[2] G. A. Razuvaev Institute of Organometallic Chemistry,undefined
来源：
Russian Chemical Bulletin | 2015年 / 64卷
关键词：
nitrone; (η; -arene)tricarbonylchromium; isoxazolidine; 1,3-dipolar cycloaddition; acrylonitrile;
D O I：
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学科分类号：
摘要：
1,3-Dipolar cycloaddition reactions of nitrones of a general formula RCH=N+(O–)R´, where R = Ph, Ph[Cr(CO)3], R´ = Me, Ph, But, with acrylonitrile were studied. The isoxazolidines obtained by these reactions were isolated and identified. The introduction in the nitrone molecule of a tricarbonylchromium group led to the increase in the regioand stereoselectivity of cycloaddition. The influence of deuterated solvents on chemical shifts of protons in the isoxazolidine ring was studied.
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页码：923 / 929
页数：6
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