Studies on the performance of multi-phased carbon/epoxy composites with nanoclay and multi-walled carbon nanotubes

被引:0
作者
Hosur M. [1 ]
Mahdi T. [1 ]
Jeelani S. [1 ]
机构
[1] Materials Science and Engineering, Tuskegee University, Tuskegee, 36088, AL
基金
美国国家科学基金会;
关键词
Carbon nanotubes; Carbon/epoxy composites; Glass transition temperature; Nanoclay; Nanocomposites; Storage modulus;
D O I
10.1007/s41939-018-0017-9
中图分类号
学科分类号
摘要
In this study, both nanoclay and COOH-functionalized multi-walled carbon nanotubes (MWCNTs) were mixed with SC-15 epoxy resin system, individually as well as together, referred as binary nanoparticles. Resulting nanocomposite was used to prepare multi-phase carbon/epoxy composites. Composites were characterized for their thermal, thermo-mechanical, tensile, and flexural properties. Failure modes of tensile and flexural samples were determined through optical and scanning electron microscopy. Properties of multi-phased nanocomposites were compared with those of carbon/epoxy composites with no nanoparticles, referred to as neat samples. While all nanophased samples exhibited better properties compared to the neat samples, composites with binary nanoparticles exhibited the best properties. Their flexural strength and modulus increased about 30 and 31%, respectively. Tensile strength, modulus, and strain to failure increased by about 28, 27, and 40%, respectively. In addition, they exhibited about 40, 44, and 19% improvement in storage modulus, loss modulus, and glass transition temperature, respectively. Coefficient of thermal expansion (CTE), when measured through thickness, decreased by about 15 and 40%, before and after glass transition temperature, respectively. Morphological and microscopic analyses exhibit higher interfacial adhesion of resin and fibers when matrix is modified with nanoparticles. © 2018, Springer International Publishing AG, part of Springer Nature.
引用
收藏
页码:255 / 268
页数:13
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共 30 条
[11]  
Iqbal K., Khan S.U., Munir A., Kim J.K., Impact damage resistance of CFRP with nanoclay-filled epoxy matrix, Compos Sci Technol, 69, 11-12, pp. 1949-1957, (2009)
[12]  
Jahan N., Narteh A., Hosur M., Rahman M., Jeelani S., Effect of carboxyl functionalized MWCNTs on the cure behavior of epoxy resin, Open J Compos Mater, 3, 2A, pp. 40-47, (2013)
[13]  
Jia X., Liu B., Huang L., Hui D., Yang X., Numerical analysis of synergistic reinforcing effect of silica nanoparticle-MWCNT hybrid on epoxy-based composites, Composites B, 54, pp. 133-137, (2013)
[14]  
Kostopoulos V., Baltopoulos A., Karapappas P., Vavouliotis A., Paipetis A., Impact and after-impact properties of carbon fibre reinforced composites enhanced with multi-wall carbon nanotubes, Compos Sci Technol, 70, 4, pp. 553-563, (2010)
[15]  
Lee S.K., Bai B.C., Im J.S., In S.J., Lee Y.S., Flame retardant epoxy complex produced by addition of montmorillonite and carbon nanotube, J Ind Eng Chem, 16, 6, pp. 891-895, (2010)
[16]  
Lu M., Lau K., Tam W.Y., Liao K., Enhancement of Vicker’s hardness of nanoclay-supported nanotube reinforced novel polymer composites, Carbon, 44, 2, pp. 383-386, (2006)
[17]  
Morsy M.S., Alsayed S.H., Aqel M., Hybrid effect of carbon nanotube and nano-clay on physico-mechanical properties of cement mortar, Constr Build Mater, 25, 1, pp. 145-149, (2011)
[18]  
Prasad M.S.S., Venkatesha C.S., Jayaraju T., Experimental methods of determining fracture toughness of fiber reinforced polymer composites under various loading conditions, J Miner Mater Charact Eng, 10, 13, pp. 1263-1275, (2011)
[19]  
Rahman M.M., Zainuddin S., Hosur M.V., Malone J.E., Salam M.B., Kumar A., Jeelani S., Improvements in mechanical and thermo-mechanical properties of e-glass/epoxy composites using amino functionalized MWCNTs, Compos Struct, 94, 8, pp. 2397-2406, (2012)
[20]  
Rahman M.M., Zainuddin S., Hosur M.V., Robertson C.J., Kumar A., Trovillion J., Jeelani S., Effect of NH <sub>2</sub> -MWCNTs on crosslink density of epoxy matrix and ILSS properties of E-glass/epoxy composites, Compos Struct, 95, pp. 213-221, (2013)