New Synthesis Method of N-Monosubstituted Ammonium-closo-Decaborates

被引：0
|
作者：
A. P. Zhdanov
V. V. Voinova
I. N. Klyukin
A. S. Kubasov
K. Yu. Zhizhin
N. T. Kuznetsov
机构：
[1] Kurnakov Institute of General and Inorganic Chemistry of the Russian Academy of Sciences,
[2] Lobachevsky State University of Nizhni Novgorod,undefined
来源：
Journal of Cluster Science | 2019年 / 30卷
关键词：
Nitrilium derivative; Boron cluster; -decaborate; Reduction process;
D O I：
暂无
中图分类号：
学科分类号：
摘要：
In work, the process of interaction of nitrilium derivatives of the closo-decaborate anion with lithium aluminum hydride was studied. Reduction process proceeds under mild conditions and leads to the formation of N-alkylammonium-closo-decaborate with high yields and selectivity. For the structure of (NnBu4)[2-B10H9NH2CH2CH3] was confirmed by single-crystal X-ray diffraction.
引用
收藏
页码：1327 / 1333
页数：6
相关论文
共 50 条
  • [41] Synthesis of N-monosubstituted ureas in a mixture of choline chloride and aluminium nitrate as a simple, efficient, and selective process
    Mohammadreza Jafari
    Atefeh Darvishi
    Akbar Heydari
    Monatshefte für Chemie - Chemical Monthly, 2023, 154 : 1295 - 1306
  • [42] Synthesis of N-monosubstituted ureas in a mixture of choline chloride and aluminium nitrate as a simple, efficient, and selective process
    Jafari, Mohammadreza
    Darvishi, Atefeh
    Heydari, Akbar
    MONATSHEFTE FUR CHEMIE, 2023, 154 (11): : 1295 - 1306
  • [43] REGIOSELECTIVE SYNTHESIS OF 1,3,5-TRISUBSTITUTED PYRAZOLES BY THE REACTION OF N-MONOSUBSTITUTED HYDRAZONES WITH NITROOLEFINS
    Deng, Xiaohu
    Mani, Neelakandha S.
    ORGANIC SYNTHESES, 2008, 85 : 179 - +
  • [44] Nano cerium oxide as a recyclable catalyst for the synthesis of N-monosubstituted ureas with the aid of acetaldoxime as an effective water surrogate
    Sajadi, S. Mohammad
    Maham, Mehdi
    JOURNAL OF CHEMICAL RESEARCH, 2013, (10) : 623 - 625
  • [45] New methods of preparation of hydroxy-closo-decaborates [B10H10 − n(OH)n]2− (n = 1, 2)
    I. N. Klyukin
    A. P. Zhdanov
    G. A. Razgonyaeva
    K. Yu. Zhizhin
    N. T. Kuznetsov
    Russian Journal of Inorganic Chemistry, 2013, 58 : 1395 - 1399
  • [46] Synthesis of 3-heteroalkyl-2-N-organylaminothiophenes.: The first proof for amino-imino tautomerism of N-monosubstituted aminothiophenes
    Brandsma, L
    Vvedensky, VY
    Nedolya, NA
    Tarasova, OA
    Trofimov, BA
    TETRAHEDRON LETTERS, 1998, 39 (16) : 2433 - 2436
  • [47] Metal-Free Stereoselective Synthesis of (E)- and (Z)N-Monosubstituted β-Aminoacrylates via Condensation Reactions of Carbamates
    Pollack, Scott R.
    Dion, Amelie
    JOURNAL OF ORGANIC CHEMISTRY, 2021, 86 (17): : 11748 - 11762
  • [48] New methods of preparation of hydroxy-closo-decaborates [B10H10-n (OH)n ]2- (n=1, 2)
    Klyukin, I. N.
    Zhdanov, A. P.
    Razgonyaeva, G. A.
    Zhizhin, K. Yu
    Kuznetsov, N. T.
    RUSSIAN JOURNAL OF INORGANIC CHEMISTRY, 2013, 58 (12) : 1395 - 1399
  • [49] New Method for Synthesis of N-Borylated Amino Acids Based on closo-Decaborate and closo-Dodecaborate Anions
    Nelyubin, A., V
    Selivanov, N. A.
    Bykov, A. Yu
    Klyukin, I. N.
    Kubasov, A. S.
    Zhdanov, A. P.
    Zhizhin, K. Yu
    Kuznetsov, N. T.
    RUSSIAN JOURNAL OF INORGANIC CHEMISTRY, 2022, 67 (11) : 1776 - 1784
  • [50] New Method for Synthesis of N-Borylated Amino Acids Based on closo-Decaborate and closo-Dodecaborate Anions
    A. V. Nelyubin
    N. A. Selivanov
    A. Yu. Bykov
    I. N. Klyukin
    A. S. Kubasov
    A. P. Zhdanov
    K. Yu. Zhizhin
    N. T. Kuznetsov
    Russian Journal of Inorganic Chemistry, 2022, 67 : 1776 - 1784
12345