New Synthesis Method of N-Monosubstituted Ammonium-closo-Decaborates

被引：0

作者：

A. P. Zhdanov

V. V. Voinova

I. N. Klyukin

A. S. Kubasov

K. Yu. Zhizhin

N. T. Kuznetsov

机构：

[1] Kurnakov Institute of General and Inorganic Chemistry of the Russian Academy of Sciences,

[2] Lobachevsky State University of Nizhni Novgorod,undefined

来源：

Journal of Cluster Science | 2019年 / 30卷

关键词：

Nitrilium derivative; Boron cluster; -decaborate; Reduction process;

D O I：

暂无

中图分类号：

学科分类号：

摘要：

In work, the process of interaction of nitrilium derivatives of the closo-decaborate anion with lithium aluminum hydride was studied. Reduction process proceeds under mild conditions and leads to the formation of N-alkylammonium-closo-decaborate with high yields and selectivity. For the structure of (NnBu4)[2-B10H9NH2CH2CH3] was confirmed by single-crystal X-ray diffraction.

引用

页码：1327 / 1333

页数：6

共 50 条

[21] Synthesis of N-Monosubstituted Sulfondiimines by Metal-free Iminations of Sulfilimium Salts
Passia, Marco T. T.
Bormann, Niklas
Ward, Jas S. S.
Rissanen, Kari
Bolm, Carsten
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2023, 62 (29)
[22] SYNTHESIS OF N-MONOSUBSTITUTED O-ACYLHYDROXYLAMINES .38. HYDROXYLAMINE DERIVATIVES
ZINNER, G
HITZE, M
ARCHIV DER PHARMAZIE UND BERICHTE DER DEUTSCHEN PHARMAZEUTISCHEN GESSELSCHAFT, 1969, 302 (12): : 916 - &
[23] A straightforward synthesis of N-monosubstituted α-keto amides via aerobic benzylic oxidation of amides
Shao, Jun
Huang, Xiaomei
Wang, Siyuan
Liu, Bingxin
Xu, Bin
TETRAHEDRON, 2012, 68 (02) : 573 - 579
[24] A new approach to the synthesis of N-monosubstituted aniline and its derivatives viaβ-cyclodextrin host-guest complexes
Min Zhang~(a
Chinese Chemical Letters, 2008, (10) : 1139 - 1142
[25] A new approach to the synthesis of N-monosubstituted aniline and its derivatives via β-cyclodextrin host-guest complexes
Zhang, Min
Gao, Yong
Hu, Rong Zu
Shi, Zhen
CHINESE CHEMICAL LETTERS, 2008, 19 (10) : 1139 - 1142
[26] SYNTHESIS OF COPPER(II) AND NICKEL(II) COMPLEXES OF SEVERAL N-MONOSUBSTITUTED OXAMIDE DERIVATIVES
NONOYAMA, K
OJIMA, H
NONOYAMA, M
INORGANICA CHIMICA ACTA, 1976, 20 (02) : 127 - 132
[27] SYNTHESIS OF N-SUBSTITUTED IMINOSULFINIC ACID-CHLORIDES - OXIDATIVE CHLORINATION OF N-MONOSUBSTITUTED SULFENAMIDES
MARKOVSKII, LN
DUBININA, TN
LEVCHENKO, ES
PENKOVSKII, VV
ZHURNAL ORGANICHESKOI KHIMII, 1976, 12 (05): : 1049 - 1054
[28] ENAMINES OF N-METHYL AND N-PHENYLPIPERAZINES . SYNTHESIS OF DISSYMETRIC N,N'-DISUBSTITUTED AND N-MONOSUBSTITUTED PIPERAZINES
MAZARGUIL, H
LATTES, A
COMPTES RENDUS HEBDOMADAIRES DES SEANCES DE L ACADEMIE DES SCIENCES SERIE C, 1968, 267 (12): : 724 - +
[29] Asymmetric synthesis of optically active phthalides using the lithiated chiral N-monosubstituted benzamides
Matsui, S
Uejima, A
Suzuki, Y
NIPPON KAGAKU KAISHI, 1996, (02) : 154 - 159
[30] Green synthesis, optical properties and catalytic activity of silver nanoparticles in the synthesis of N-monosubstituted ureas in water
Nasrollahzadeh, Mahmoud
Babaei, Ferydon
Sajadi, S. Mohammad
Ehsani, Ali
SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY, 2014, 132 : 423 - 429

← 1 2 3 4 5 →