A thermochemical study of aqueous solutions of sodium diclophenac at 293.15–318.15 K

被引：0
|
作者：
N. G. Manin
G. L. Perlovich
A. N. Manin
A. Fini
机构：
[1] Russian Academy of Sciences,Institute of the Solution Chemistry
[2] Ivanovo State University of Chemical Technology,Institute of Chemical Sciences
[3] University of Bologna,undefined
来源：
Russian Journal of Physical Chemistry A | 2007年 / 81卷
关键词：
Enthalpy; Thermodynamic Characteristic; Endothermic Effect; Thermochemical Data; Thermochemical Study;
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学科分类号：
摘要：
The enthalpies of solution and dilution of aqueous solutions of sodium diclophenac were measured at 293.15–318.15 K on an isoperibolic calorimeter. The content of the electrolyte determined by its solubility did not exceed 0.035–0.057 mol/kg solvent depending on temperature. The Pitzer model was used to obtain virial coefficients that allowed us to calculate a wide range of excess thermodynamic properties of both solution and its components.
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页码：1062 / 1070
页数：8
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