Asymmetric Diels-Alder reactions of cyclopentadiene in the synthesis of chiral norbornene derivatives

被引：0
作者：
E. G. Mamedov
E. I. Klabunovskii
机构：
[1] National Academy of Sciences of Azerbaidjan,Institute of Petrochemical Processes
[2] Russian Academy of Sciences,Zelinskii Institute of Organic Chemistry
来源：
Russian Journal of Organic Chemistry | 2008年 / 44卷
关键词：
Cyclopentadiene; Alder Reaction; Optical Yield; Menthyl; Chiral Catalyst;
D O I：
暂无
中图分类号：
学科分类号：
摘要：
The review discusses available data on asymmetric Diels-Alder reactions of cyclopentadiene, which were published in the past decade. Both noncatalytic and catalytic (in the presence of achiral and chiral catalysts) versions of these reactions are considered. Effects of various factors on the chemical and optical yields, stereoselectivity, and optical purity of the Diels-Alder adducts are analyzed. Prospects in the development of this field of organic chemistry are examined.
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页码：1097 / 1120
页数：23
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