Reactions of octahydroacridine-4-carbonitrile (carboxamide) with electrophilic reagents

被引：0
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作者：
Ekaterina V. Zaliznaya
Oleg K. Farat
Nikolay Yu. Gorobets
Viktor I. Markov
Roman I. Zubatyuk
Aleksandr V. Mazepa
Elena V. Vashchenko
机构：
[1] Ukrainian State University of Chemical Technology,State Scientific Institution “Institute for Single Crystals”
[2] National Academy of Sciences of Ukraine,A. V. Bogatskii Physicochemical Institute
[3] National Academy of Sciences of Ukraine,undefined
来源：
Chemistry of Heterocyclic Compounds | 2015年 / 51卷
关键词：
diazonium salt; octahydroacridines; azo coupling; electrophilic substitution; Japp–Klingemann reaction; radical; radical reactions;
D O I：
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学科分类号：
摘要：
[graphic not available: see fulltext]Octahydroacridine-4-carbonitrile (carboxamide) was shown to react with aryldiazonium salts and other electrophilic reagents in acidic and neutral media. The reactions occurred at the methine carbon atom, forming the corresponding 4-functionalized derivatives. The obtained azo compounds decomposed at 140–155°С with elimination of nitrogen and gave products formed by the reactions of radical intermediates.
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页码：327 / 333
页数：6
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