A new layered iron fluorophosphate

被引：5
作者：
Choudhury A. [1 ,2 ]
机构：
[1] Chemistry and Physics of Materials Unit, Jawaharlal Nehru Centre for Advanced Scientific Research, Bangalore 560 064, Jakkur PO
[2] Solid State and Structural Chemistry Unit, Indian Institute of Science
来源：
Journal of Chemical Sciences | 2002年 / 114卷 / 2期
关键词：
Hydrothermal synthesis; Layered iron phosphate; Open-framework materials;
D O I：
10.1007/BF02704302
中图分类号：
学科分类号：
摘要：
A new iron fluorophosphate of the composition, [C6N4H21] [Fe2F2(HPO4)3][H2PO4]·2H2O, I has been prepared by the hydrothermal route. This compound contains iron fluorophosphate layers and the H2PO4- anions are present in the interlayer space along with the protonated amine and water molecules. The compound crystallizes in the monoclinic space group P21/c. (a = 13.4422(10) Å, b = 9.7320(10) Å, c = 18.3123(3) Å, β = 92.1480°, V = 2393.92(5) Å3, Z = 4, M = 719.92, dcalc. = 1.997 g cm-3, R1 = 0.03 and wR2 = 0.09).
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页码：93 / 105
页数：12
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