Oxidation of 5-aminouracil with molecular oxygen in aqueous solution in the presence of copper(II) chloride

被引：0
作者：
Yu. I. Murinov
V. Yu. Mishinkin
O. V. Akchurina
S. A. Grabovskii
N. N. Kabal’nova
机构：
[1] Russian Academy of Sciences,Ufa Institute of Chemistry
来源：
Russian Journal of General Chemistry | 2017年 / 87卷
关键词：
molecular oxygen; 5-aminouracil derivatives; copper(II) ions; copper(II) complexes; oxidation;
D O I：
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学科分类号：
摘要：
5-Aminouracil was found to form a six-coordinate copper(II) complex in aqueous solution and undergo oxidation to 5,5,6-trihydroxypyrimidine-2,4(1H,3H)-dione in the presence of molecular oxygen. A scheme was proposed for the fixation and activation of molecular oxygen on six-coordinate copper(II) complex with 5-aminouracil. The effect of the ligand structure on the rate of its oxidation with molecular oxygen in aqueous solution in the presence of copper(II) ions was shown.
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页码：1667 / 1674
页数：7
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