Vibrational linestrengths for the ground and first excited electronic states of HeH2+

被引:0
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作者
M. Šindelka
V. Špirko
W. P. Kraemer
机构
[1] Academy of Sciences of the Czech Republic and Center for Complex Molecular Systems and Biomolecules,J. Heyrovský Institute of Physical Chemistry
[2] Max-Planck Institute of Astrophysics,undefined
来源
Theoretical Chemistry Accounts | 2003年 / 110卷
关键词
Vibrational line strength – HeH; – Electric dipole moment surface – Transition dipole moment;
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摘要
Together with recent improved potential-energy surface calculations for the ground (˜X) and first excited (Ã) electronic states of HeH2+, the electric dipole moment surfaces for each state and the transition dipole moments connecting the two states were evaluated for the entire range of the energy calculations. Using these functions the linestrengths of all dipole-allowed transitions between the bound vibrational levels within each of the two states (˜X→˜X) and (Ã→Ã) as well as between them (Ã→˜X) are evaluated here. These data are believed to be useful both in the experimental search for the yet unobserved molecular spectra of HeH2+ and in evaluating theoretical rates for the radiative association or photodissociation processes involving the two lowest electronic states of the ion.
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页码:170 / 175
页数:5
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