One-step synthesis of cyclohexylamine from benzene, hydroxylamine and hydrogen over vanadium and ruthenium catalysts

被引：1
|
作者：
Aina Yang
Tong Wang
Zhihui Li
Yuanyuan Xu
Liya Gao
Dongsheng Zhang
Shufang Wang
Xinqiang Zhao
Yanji Wang
机构：
[1] Hebei University of Technology,School of Chemical Engineering and Technology
[2] Hebei University of Technology,School of Energy and Environmental Engineering
[3] The University of New South Wales,School of Chemistry
来源：
Research on Chemical Intermediates | 2018年 / 44卷
关键词：
Benzene; Hydroxylamine; Cyclohexylamine; Bi-functional catalyst; Vanadium; Ruthenium;
D O I：
暂无
中图分类号：
学科分类号：
摘要：
In this study,we investigated a one-step process for synthesis of cyclohexylamine from benzene, hydroxylamine and hydrogen under mild conditions. A bi-functional supported catalyst Ru–V2O5/MCM-41 was prepared and characterized by nitrogen adsorption/desorption, XRD, SEM, ICP and XPS. The results showed that the suitable Ru and V2O5 content is 3 and 10 wt%, respectively. The one-step reaction was strongly dependent on catalyst amount, solvent, hydrogen pressure, reaction temperature and time. Relatively high yield (20%) and selectivity (77%) of the product cyclohexylamine were obtained under optimized reaction conditions.
引用
收藏
页码：339 / 354
页数：15
相关论文
共 50 条
  • [21] A convenient one-step synthesis of alkenyl-phosphonio complexes of ruthenium(II), rhodium(III) and iridium(III)
    Yamamoto, Y
    Ogata, K
    Kuge, K
    Tatsumi, K
    INORGANIC CHEMISTRY COMMUNICATIONS, 2002, 5 (10) : 862 - 864
  • [22] Reaction kinetics of phenol synthesis through one-step oxidation of benzene with N2O over Fe-ZSM-5 zeolite
    Mi, Guanjie
    Li, Jianwei
    Zhang, Jie
    Chen, Biaohua
    KOREAN JOURNAL OF CHEMICAL ENGINEERING, 2010, 27 (06) : 1700 - 1706
  • [23] One-step selective oxidation over a Pd-based catalytic membrane; evaluation of the oxidation of benzene to phenol as a model reaction
    Vulpescu, GD
    Ruitenbeek, M
    van Lieshout, LL
    Correia, LA
    Meyer, D
    Pex, PPAC
    CATALYSIS COMMUNICATIONS, 2004, 5 (06) : 347 - 351
  • [24] One-step synthesis of gasoline fuels from γ-valerolactone with high selectivity over Cu/HZSM-5 bifunctional catalyst
    Wang, Hongtao
    Wu, Yushan
    Li, Yanzhi
    Peng, Jiebang
    Gu, Xiang-Kui
    Ding, Mingyue
    APPLIED CATALYSIS B-ENVIRONMENTAL, 2021, 296
  • [25] Effect of Microwave Irradiation on Synthesis of Phenol from Benzene Over Activated Carbon as Supported Catalysts
    Liu, T.
    Hou, J. H.
    ASIAN JOURNAL OF CHEMISTRY, 2014, 26 (15) : 4815 - 4818
  • [26] One-step hydrogenation-esterification of furfural and acetic acid over bifunctional Pd catalysts for bio-oil upgrading
    Yu, Wanjin
    Tang, Yang
    Mo, Liuye
    Chen, Ping
    Lou, Hui
    Zheng, Xiaoming
    BIORESOURCE TECHNOLOGY, 2011, 102 (17) : 8241 - 8246
  • [27] New research progress on bifunctional catalysts for one-step direct production of low carbon olefins from syngas
    Zao H.-J.
    Yao J.-G.
    Liu J.
    Chen G.-Y.
    Yi W.-M.
    Xiong J.-L.
    Ranliao Huaxue Xuebao/Journal of Fuel Chemistry and Technology, 2023, 51 (01): : 19 - 33
  • [28] One-step synthesis of dimethyl ether from syngas on ordered mesoporous copper incorporated alumina
    Wang, Yan
    Chen, Yuexian
    Yu, Feng
    Pan, Dahai
    Fan, Binbin
    Ma, Jinghong
    Li, Ruifeng
    JOURNAL OF ENERGY CHEMISTRY, 2016, 25 (05) : 775 - 781
  • [29] One-step electroplating of palladium-copper alloy layers on a vanadium membrane for hydrogen separation: Quick, easy, and low-cost preparation
    Endo, Naruki
    Dezawa, Norikazu
    Komo, Yasuhiro
    Maeda, Tetsuhiko
    INTERNATIONAL JOURNAL OF HYDROGEN ENERGY, 2021, 46 (64) : 32570 - 32576
  • [30] Highly Selective Synthesis of Phenol from Benzene over a Vanadium-Doped Graphitic Carbon Nitride Catalyst
    Ding, Guodong
    Wang, Weitao
    Jiang, Tao
    Han, Buxing
    Fan, Honglei
    Yang, Guanying
    CHEMCATCHEM, 2013, 5 (01) : 192 - 200
12345