Electrical conductivity of Cs2CuCl4 crystals

被引：0
作者：
N. I. Sorokin
机构：
[1] Russian Academy of Sciences,Shubnikov Institute of Crystallography
来源：
Crystallography Reports | 2016年 / 61卷
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摘要：
The electrical conductivity of Cs2CuCl4 single crystals, synthesized by crystallization from aqueous solutions in the CsCl–CuCl2–H2O system, has been investigated. The temperature dependence of the electrical conductivity of crystals in a temperature range of 338–584 K exhibits no anomalies. The electrical transfer activation enthalpy is ΔHσ = 0.72 ± 0.05 eV and the conductivity is σ = 3 × 10–4 S/cm at 584 K. The most likely carriers in Cs2CuCl4 are Cs+ cations, which transfer electric charge according to the vacancy mechanism.
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页码：466 / 468
页数：2
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