The thermodynamic characteristics of sublimation of chromium trichloride

被引：0
作者：
V. A. Titov
E. E. Grinberg
机构：
[1] Russian Academy of Sciences,Institute of Inorganic Chemistry, Siberian Division
[2] Research Institute of Chemical Reagents and Special-Purity Substances,undefined
来源：
Russian Journal of Physical Chemistry | 2006年 / 80卷
关键词：
Entropy; Physical Chemistry; Chromium; Enthalpy; Chlorine;
D O I：
暂无
中图分类号：
学科分类号：
摘要：
The sublimation of stoichiometric chromium trichloride was experimentally studied by the static method of vapor pressure measurements. The main reaction was found to be CrCl3(cr) = CrCl3(g). The enthalpy and entropy of this reaction were calculated. Sublimation was also performed in the presence of excess chlorine. The thermodynamic characteristics of the reaction 2CrCl3(g) + Cl2 = 2CrCl4(g) were estimated.
引用
收藏
页码：689 / 692
页数：3
相关论文
共 50 条
[41]   High-temperature thermodynamic characteristics of Ho5Ge3 [J].
Gorbachuk, N. P. ;
Sidorko, V. R. ;
Kulikov, L. M. ;
Obushenko, I. M. ;
Kirienko, S. N. .
POWDER METALLURGY AND METAL CERAMICS, 2007, 46 (9-10) :478-482
[42]   Thermodynamic characteristics of the acid dissociation of dopamine hydrochloride in water-ethanol solutions [J].
S. F. Ledenkov ;
V. N. Vandyshev ;
A. S. Molchanov .
Russian Journal of Physical Chemistry A, 2012, 86 :959-964
[43]   Characteristics of Voltammetric Determination and Speciation of Chromium - A Review [J].
Bobrowski, Andrzej ;
Krolicka, Agnieszka ;
Zarebski, Jerzy .
ELECTROANALYSIS, 2009, 21 (13) :1449-1458
[44]   Thermodynamic Analysis of the Silicon Effect on Chemical and Electrochemical Stability of Iron–Chromium Alloys [J].
A. G. Tyurin .
Protection of Metals, 2004, 40 :14-22
[45]   Thermodynamic analysis of sorption isotherms of chromium(VI) anionic species on reed biomass [J].
Rawajfih, Z. ;
Nsour, N. .
JOURNAL OF CHEMICAL THERMODYNAMICS, 2008, 40 (05) :846-851
[46]   Thermodynamic assessment of the effect of chromium and molybdenum on the passivability of nickel-base alloys [J].
Tyurin, AG .
PROTECTION OF METALS, 2003, 39 (06) :568-574
[47]   Thermodynamic Assessment of the Effect of Chromium and Molybdenum on the Passivability of Nickel-Base Alloys [J].
A. G. Tyurin .
Protection of Metals, 2003, 39 :568-574
[48]   Thermodynamic Interaction between Chromium and Sulfur in High Cr Containing Liquid Iron [J].
Do, Kyung-Hyo ;
Kim, Young-Dae ;
Kim, Dong-Sik ;
Chung, Yongsug ;
Pak, Jong-Jin .
ISIJ INTERNATIONAL, 2015, 55 (05) :934-939
[49]   Thermodynamic Interaction between Chromium and Phosphorus in High Cr Containing Liquid Iron [J].
Do, Kyung-Hyo ;
Nam, Hong-Sik ;
Jang, Jung-Mock ;
Kim, Dong-Sik ;
Pak, Jong-Jin .
ISIJ INTERNATIONAL, 2017, 57 (08) :1334-1339
[50]   Synthesis and thermodynamic characteristics of LaSrNiO4 [J].
Matskevich, NI ;
Kuznetsov, FA ;
Feil, D ;
Range, KJ .
THERMOCHIMICA ACTA, 1998, 319 (1-2) :1-5
12345