The thermodynamic characteristics of sublimation of chromium trichloride

被引：0
|
作者：
V. A. Titov
E. E. Grinberg
机构：
[1] Russian Academy of Sciences,Institute of Inorganic Chemistry, Siberian Division
[2] Research Institute of Chemical Reagents and Special-Purity Substances,undefined
来源：
Russian Journal of Physical Chemistry | 2006年 / 80卷
关键词：
Entropy; Physical Chemistry; Chromium; Enthalpy; Chlorine;
D O I：
暂无
中图分类号：
学科分类号：
摘要：
The sublimation of stoichiometric chromium trichloride was experimentally studied by the static method of vapor pressure measurements. The main reaction was found to be CrCl3(cr) = CrCl3(g). The enthalpy and entropy of this reaction were calculated. Sublimation was also performed in the presence of excess chlorine. The thermodynamic characteristics of the reaction 2CrCl3(g) + Cl2 = 2CrCl4(g) were estimated.
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页码：689 / 692
页数：3
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