Crown ether–ionic liquid-based extraction chromatographic resin for separation of 90Y from 90Sr

被引:0
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作者
Yu Zou
Juncheng Liang
Taiwei Chu
机构
[1] Peking University,Beijing National Laboratory for Molecular Sciences, Radiochemistry and Radiation Chemistry Key Laboratory of Fundamental Science, College of Chemistry and Molecular Engineering
[2] National Institute of Metrology,undefined
关键词
Ionic liquid; Crown ether; Separation of Y from Sr; Extraction column chromatography; Chromatographic resin;
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学科分类号
摘要
90Y was separated from 90Sr using an extraction chromatographic resin consisting of 4, 4′(5′)-bis-t-butylcyclohexano-18-crown-6 (DtBuCH18C6), 1-ethyl-3-methylimidazolium bis(trifluoromethanesulfonyl) amide (C2mimNTf2), and a polymer (Amberlite XAD-7). Ionic liquid was introduced into the column to improve the separation efficiency. The column showed an excellent performance for the separation of Y from Sr. After the separation, the ratio of 90Sr/90Y was <2.0 × 10−5; the column was recycled for >18 times. This study provides preliminary results on columns to produce 90Y with a high purity in radiopharmaceuticals.
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页码:1643 / 1648
页数:5
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