Structure and the electrical and magnetic properties of perovskite-like GdxCu3V4O12 oxide

被引：0
作者：
N. I. Kadyrova
Yu. G. Zainulin
A. P. Tyutyunnik
N. V. Mel’nikova
I. S. Ustinova
A. V. Korolev
机构：
[1] Russian Academy of Sciences,Institute of Solid State Chemistry, Ural Branch
[2] Ural Federal University,Institute of Metal Physics, Ural Branch
[3] Russian Academy of Sciences,undefined
来源：
Bulletin of the Russian Academy of Sciences: Physics | 2012年 / 76卷 / 7期
关键词：
Perovskite; Magnetic Susceptibility; Effective Magnetic Moment; CaCu; Platinum Foil;
D O I：
10.3103/S1062873812070167
中图分类号：
学科分类号：
摘要：
A new perovskite-like compound GdxCu3V4O12 (x = 0.67−0.73) is synthesized under high pressures (P = 4−9 GPa) and at high temperatures (T = 1000°C). Its structure (space group Im3, Z = 2, a = 7.2930(5) Å) is estrablished by X-ray analysis. The bond lengths and bond angles are determined. The temperature dependences of electrical resistivity (10–300 K) and magnetic susceptibility are studied. The high-pressure GdxCu3V4O12 phase is found to have a semi-conductor type of conductivity and paramagnetic properties.
引用
收藏
页码：744 / 746
页数：2
相关论文
共 24 条
  • [1] Vasil’ev A.N.(2007)undefined Fiz. Nizk. Temp. 33 1181-767
  • [2] Volkova O.S.(2008)undefined Inorg. Chem. 47 2706-undefined
  • [3] Xiang H.(2008)undefined Inorg. Chem. 47 8562-undefined
  • [4] Wu Z.(2000)undefined J. Solid State Chem. 151 323-undefined
  • [5] Shimakava Y.(2007)undefined Russ. J. Inorg. Chem. 52 329-undefined
  • [6] Subramanian M.A.(1999)undefined Phys. Rev. Lett. 82 3164-undefined
  • [7] Li D.(2008)undefined Angew. Chem., Int. Ed. 47 7032-undefined
  • [8] Duan N.(2009)undefined Phys. Rev. B 80 125105-undefined
  • [9] Reisner B.A.(1976)undefined Acta Crystallogr. A 32 751-undefined
  • [10] Sleight A.W.(undefined)undefined undefined undefined undefined-undefined
123