Synthesis, Structure and Luminescence Property of Cadmium(II) Coordination Polymer with Mixed 5-(Oxidediphenylphosphino)isophthalic Acid and 4,4′-Bipyridine Ligands

被引:0
作者
Wen-Wen Shan
Xiao Mi
Jia-Yi Pu
Shi-Le Mei
Kai-Hui Li
Chong-Zhen Mei
机构
[1] Institute of Environmental and Municipal Engineering,
[2] North China University of Water Conservancy and Electric Power,undefined
来源
Journal of Inorganic and Organometallic Polymers and Materials | 2013年 / 23卷
关键词
5-(Oxidediphenylphosphino)isophthalic acid; Cd(II); Hydrogen bond; Eight-member ring; Luminescence property;
D O I
暂无
中图分类号
学科分类号
摘要
A new metal–organic framework {[Cd(L)(4,4′-bpy)]2·5H2O}n (1) had been synthesized by hydrothermal reaction of 5-(oxidediphenylphosphino)isophthalic acid, Cd(II) nitrate, NaOH and 4,4′-bipyridine (4,4′-bpy) as co-ligand. The novel compound was characterized by single crystal X-ray diffractometry as well as FTIR spectrum. Adjacent eight-member (C2Cd2O4) rings are connected each other through pairs of L2− ligands to result in a 1D double chain. Such ribbons are interconnected together by 4,4′-bpy to generate a 2D pillared layer, which are further held together by rich O–H···O hydrogen bonds to give a 3D supramolecular network. Solvent water molecules play an important role to bridge adjacent layers to form a 3D supramolecular architecture. The luminescence property and thermogravimetric analysis of title complex were investigated.
引用
收藏
页码:533 / 538
页数:5
相关论文
共 141 条
[1]  
Rowsell JLC(2004)undefined Microporous Mesoporous Mater. 73 3-undefined
[2]  
Yaghi OM(2005)undefined Angew. Chem. Int. Ed. 44 5824-undefined
[3]  
Wang XL(2004)undefined J. Am. Chem. Soc. 126 1308-undefined
[4]  
Qin C(2002)undefined Chem. Eur. J. 8 4811-undefined
[5]  
Wang EB(2005)undefined Cryst. Growth Des. 5 1199-undefined
[6]  
Li Y-G(2006)undefined Cryst. Growth Des. 6 2369-undefined
[7]  
Su ZM(2008)undefined Cryst. Growth Des. 8 3706-undefined
[8]  
Xu L(2010)undefined CrystEngComm. 12 2157-undefined
[9]  
Carlucci L(2010)undefined CrystEngComm. 12 2179-undefined
[10]  
Pan L(2003)undefined Eur. J. Inorg. Chem. 9 2965-undefined