Synthesis and Crystal Structure of the 2-D Polymer {Cu(bipy)Pt(CN)4}∞ and Its Relationship to the Tetranuclear Compound [{Cu(bipy)(H2 O)Pt(CN)4}2]·2H2O

被引：0

作者：

Larry R. Falvello

Raquel Garde

Milagros Tomás

机构：

[1] University of Zaragoza-C.S.I.C.,Department of Inorganic Chemistry and Aragon Materials Science Institute

来源：

Journal of Cluster Science | 2000年 / 11卷

关键词：

polymer; cluster; hydrogen bonds; Pt; Cu;

D O I：

暂无

中图分类号：

学科分类号：

摘要：

The reaction of (NBu4)2[Pt(CN)4] with Cu(NO3)2·2.5H2O and bipy in stoichiometric ratio in methanol solution yields the 2-D polymer {Cu(bipy)Pt(CN)4}∞. The influence of water molecules and hydrogen bonding on the formation of a 2-D polymeric structure versus a tetranuclear cluster from “Cu(bipy)Pt(CN)4” units is discussed.

引用

页码：125 / 133

页数：8

共 17 条

[1]

Dunbar K. R.(1997)undefined Prog. Inorg. Chem. 45 283-undefined

[2]

Heintz R. A.(1997)undefined J. Am. Chem. Soc. 119 11894-undefined

[3]

Falvello L. R.(1968)undefined Inorg. Chim. Acta 2 313-undefined

[4]

Pascual I.(1994)undefined Acta Crystallogr., Sect. C C50 496-undefined

[5]

Tomás M.(1981)undefined Inorg. Chem. 20 4446-undefined

[6]

Urriolabeitia E. P.(undefined)undefined undefined undefined undefined-undefined

[7]

Iwamoto T.(undefined)undefined undefined undefined undefined-undefined

[8]

Nakano T.(undefined)undefined undefined undefined undefined-undefined

[9]

Morita M.(undefined)undefined undefined undefined undefined-undefined

[10]

Miyoshi T.(undefined)undefined undefined undefined undefined-undefined

← 1 2 →