Ethylene carbonate production by cyclocondensation of ethylene glycol and urea in the presence of metal oxides and metal acetylacetonates

被引：0
作者：
A. S. Lyadov
A. A. Kochubeev
E. B. Markova
S. N. Khadzhiev
机构：
[1] Russian Academy of Sciences,Topchiev Institute of Petrochemical Synthesis
来源：
Petroleum Chemistry | 2016年 / 56卷
关键词：
ethylene carbonate; ethylene glycol; urea; metal oxides; metal acetylacetonates;
D O I：
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学科分类号：
摘要：
A promising method for the production of ethylene carbonate is the cyclocondensation of ethylene glycol and urea in the presence of a catalyst. In this study, the catalytic effect of oxides and acetylacetonates of various metals on the occurrence of this reaction has been examined. It has been shown that cobalt acetylacetonate is the most effective catalyst. The effect of reaction conditions (temperature, pressure, contact time, and catalyst concentration) on the main parameters of catalytic conversion has been studied.
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页码：852 / 856
页数：4
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