Electrochemical quartz crystal microbalance study of ion transport accompanying charging-discharging of poly(pyrrole) films

被引:0
作者
György Inzelt
Vilmos Kertész
Ann-Sofi Nybäck
机构
[1] Department of Physical Chemistry,
[2] Eötvös Loránd University,undefined
[3] P.O. Box 32,undefined
[4] H-1518 Budapest 112,undefined
[5] Hungary,undefined
[6] Laboratory of Analytical Chemistry,undefined
[7] Abo Akademi University,undefined
[8] Biskopsgatan 8,undefined
[9] FIN-20500 Abo,undefined
[10] Finland,undefined
来源
Journal of Solid State Electrochemistry | 1999年 / 3卷
关键词
Key words Poly(pyrrole); Electrochemical quartz crystal microbalance; Ionic charge transport;
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摘要
Electrochemical quartz crystal microbalance studies on poly(pyrrole) electrodes revealed a complex nature of the potential-dependent sorption of ionic substances. It is found that the relative contribution of anions and cations to the overall charge transport process depends upon several factors, such as the oxidation state of the polymer, the composition of the supporting electrolyte as well as on the film thickness. The phenomena observed are discussed in terms of morphological transformations arising as a result of interactions between the polymer and the mobile substances.
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页码:251 / 257
页数:6
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