Kinetics of thermal decomposition of dimethyldioxirane in oxygen atmosphere

被引：0

作者：

S. A. Grabovski

D. V. Kazakov

N. N. Kabalnova

S. L. Khursan

V. V. Shereshovets

机构：

[1] Academy of Sciences,Institute of Organic Chemistry, Ufa Research Center of the Russian

来源：

Reaction Kinetics and Catalysis Letters | 1997年 / 62卷

关键词：

Dioxiranes; kinetics; thermolysis;

D O I：

暂无

中图分类号：

学科分类号：

摘要：

Dimethyldioxirane decomposition in oxygen atmosphere follows a first-order kinetic law. Decomposition rate constant (k, s−1) in acetone in the temperature range from 30 to 50°C has been determined as lgk=(7.1±0.9)−(16.0±1.4)/θ, θ=2.303RT kcal/mol.

引用

页码：179 / 183

页数：4

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