Synthesis and crystal structure of Cs2[(UO2)2(C2O4)3] and Cs2[UO2(C3H2O4)2] · H2O

被引：0
|
作者：
L. B. Serezhkina
E. V. Peresypkina
Ya. A. Medvedkov
A. V. Virovets
V. N. Serezhkin
机构：
[1] Samara State University,Nikolaev Institute of Inorganic Chemistry, Siberian Branch
[2] Russian Academy of Sciences,undefined
来源：
Russian Journal of Inorganic Chemistry | 2013年 / 58卷
关键词：
Uranium; Malonate; Malonic Acid; Cesium Atom; Uranium Atom;
D O I：
暂无
中图分类号：
学科分类号：
摘要：
Cs2[(UO2)2(C2O4)3] (I) and Cs2[UO2(C3H2O4)2] · H2O (II) have been synthesized and studied by X-ray diffraction. The crystals of complexes I and II are monoclinic: a = 8.1453(2) Å, b = 8.9831(2) Å, c = 11.3897(4) Å, β = 104.0950(10)°, V = 808.29(4) Å3, space group P21/n, Z = 2, and R1 = 0.0255 for I and a = 9.6998(2) Å, b = 17.8686(3) Å, c = 8.2074(2) Å, β = 97.5780(10)°, V = 1410.10(5) Å3, space group P21/c, Z = 4, and R1 = 0.0287 for II. The uranium-containing structural units of complexes I and II are [(UO2)2(C2O4)3]2− chains and [UO2(C3H2O4)2]24− dimers, which belong to the AK0.502T11 and AT11B01 crystallochemical groups (A = UO22+, K02 and T11 = C2O42−, T11 and B01 = C3H2O42−) of uranyl complexes.
引用
收藏
页码：1465 / 1469
页数：4
相关论文
共 50 条
  • [31] Synthesis and crystal structure of (CN3H6)2[UO2(OH)2(NCS)]NO3 and β-Cs3[UO2(NCS)5]
    Serezhkin, V. N.
    Peresypkina, E. V.
    Karasev, M. O.
    Virovets, A. V.
    Serezhkina, L. B.
    CRYSTALLOGRAPHY REPORTS, 2014, 59 (02) : 196 - 201
  • [32] Crystal structure of U(VI) phthalate dihydrate [UO2(OOC) 2C6H4·H2O]·H 2O
    Charushnikova I.A.
    Krot N.N.
    Starikova Z.A.
    Radiochemistry, 2004, 46 (6) : 556 - 559
  • [33] Crystal structure and IR spectroscopic study of (CN3H6)2[(UO2)2(C2O4)(CH3COO)4]
    L. B. Serezhkina
    E. V. Peresypkina
    N. A. Neklyudova
    A. V. Virovets
    V. N. Serezhkin
    Crystallography Reports, 2013, 58 : 275 - 279
  • [34] Synthesis and X-ray diffraction study of [UO2(NO3)2(H2O)2] · 2C12H18O
    L. B. Serezhkina
    A. V. Vologzhanina
    E. S. Klynin
    A. A. Korlyukov
    I. K. Moiseev
    V. N. Serezhkin
    Crystallography Reports, 2012, 57 : 252 - 257
  • [35] Synthesis and crystal structure of (CN3H6)2[UO2(OH)2(NCS)]NO3 and β-Cs3[UO2(NCS)5]
    V. N. Serezhkin
    E. V. Peresypkina
    M. O. Karasev
    A. V. Virovets
    L. B. Serezhkina
    Crystallography Reports, 2014, 59 : 196 - 201
  • [36] Synthesis and structure of [UO2(SeO4)(C2H4N4)2] · 0.5H2O
    E. V. Grechishnikova
    A. V. Virovets
    E. V. Peresypkina
    L. B. Serezhkina
    Russian Journal of Coordination Chemistry, 2006, 32 : 586 - 589
  • [37] Synthesis and structure of [UO2(SeO4)(C2H4N4)2] • 0.5H2O
    Grechishnikova, E. V.
    Virovets, A. V.
    Peresypkina, E. V.
    Serezhkina, L. B.
    RUSSIAN JOURNAL OF COORDINATION CHEMISTRY, 2006, 32 (08) : 586 - 589
  • [38] Crystal structure of uranyl μ3-oxoacetate [(UO2) 3(μ3-O)2(OOCCH3) 2(H2O)2]
    Charushnikova I.A.
    Krot N.N.
    Starikova Z.A.
    Radiochemistry, 2004, 46 (5) : 429 - 433
  • [39] The structure of compreignacite, K2[(UO2)3O2(OH)3]2(H2O)7
    Burns, PC
    CANADIAN MINERALOGIST, 1998, 36 : 1061 - 1067
  • [40] Synthesis and an X-ray diffraction study of Rb2[(UO2)2(C2O4)3]
    L. B. Serezhkina
    E. V. Peresypkina
    N. A. Neklyudova
    A. V. Virovets
    Crystallography Reports, 2010, 55 : 769 - 772
12345