Crystal structure of a tantal cluster with tetraphenylborate-anion: [Ta6Br12(H2O)6](BPh4)2·4H2O

被引:0
作者
A. V. Anyushin
M. N. Sokolov
E. V. Peresypkina
V. P. Fedin
机构
[1] Russian Academy of Sciences,A. V. Nikolaev Institute of Inorganic Chemistry, Siberian Division
[2] Novosibirsk State University,undefined
来源
Journal of Structural Chemistry | 2013年 / 54卷
关键词
tantalum; bromine; cluster; X-ray structure; hydrogen bonds;
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学科分类号
摘要
The crystal structure of the [Ta6Br12(H2O)6](BPh4)2·4H2O salt (1), obtained from Ta6Br14·7H2O and NaBPh4, is determined by X-ray crystallographic analysis. The structure contains a network of hydrogen bonds, which organizes the cluster cations into layers.
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页码:454 / 458
页数:4
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