Catalytic oxidation of furan and hydrofuran compounds. 5. Hydroxy- and ethoxydihydrofurans and ethoxyfuran - New products from the reaction of furan with hydrogen peroxide

被引：0

作者：

Poskonin V.V. ^{[1
]}

Badovskaya L.A. ^{[1
]}

Povarova L.V. ^{[1
]}

机构：

[1] Kubansk State Technological University, Krasnodar

来源：

Chemistry of Heterocyclic Compounds | 1998年 / 34卷 / 8期

关键词：

Oxidation; Hydrogen; Hydrogen Peroxide; Organic Chemistry; Furan;

D O I：

10.1007/BF02311323

中图分类号：

学科分类号：

摘要：

It was established for the first time by chromato-mass spectrometry that 2-X-5-Y-2,5-dihydrofurans (X, Y = OH, OEt) and 2-ethoxyfuran are formed during the oxidation of furan by hydrogen peroxide in a mixture of water and ethanol in the presence of VOSO4. Stable tautomeric forms of 2-hydroxy- and 2,5-dihydroxyfurans - 2(5H)-furanone and 5-ethoxy-2(5H)-furanone respectively - were isolated from the reaction mixture. A probable scheme for the main reaction paths is proposed. ©1999 Kluwer Academic/Plenum Publishers.

引用

页码：900 / 906

页数：6

共 25 条

[11] CATALYTIC OXIDATION REACTIONS OF FURAN AND HYDROFURAN COMPOUNDS 9.* CHARACTERISTICS AND SYNTHETIC POSSIBILITIES OF THE REACTION OF FURAN WITH AQUEOUS HYDROGEN PEROXIDE IN THE PRESENCE OF COMPOUNDS OF NIOBIUM(II) AND (V)
Poskonin, V. V.
CHEMISTRY OF HETEROCYCLIC COMPOUNDS, 2009, 45 (10) : 1177 - 1183
[12] Reactions of catalytic oxidation of furan and hydrofuran compounds. 8. Conversions of 2(5H)-furanone in hydrogen peroxide solutions at different pH
Ponomarenko, RI
Badovskaya, LA
Latashko, VM
KHIMIYA GETEROTSIKLICHESKIKH SOEDINENII, 2002, (09): : 1204 - 1206
[13] Catalytic oxidation of furan and hydrofuran compounds. 2. Oxidation of furfural in the hydrogen peroxide-vanadyl sulfate-sodium acetate system
Poskonin, V.V.
Badovskaya, L.A.
Chemistry of Heterocyclic Compounds, 1998, 34 (06): : 646 - 650
[14] Catalytic oxidation of furan and hydrofuran compounds. 7. Production of 2(5h)-furanone by oxidation of furfural with hydrogen peroxide and some of its transformations in aqueous solutions
Badovskaya L.A.
Latashko V.M.
Poskonin V.V.
Grunskaya E.P.
Tyukhteneva Z.I.
Rudakova S.G.
Pestunova S.A.
Sarkisyan A.V.
Chemistry of Heterocyclic Compounds, 2002, 38 (09) : 1040 - 1048
[15] Catalytic oxidation of furan and hydrofuran compounds. 3. Synthesis of 2,5-diethoxy-2,5-dihydrofuran in the system furan hydrogen peroxide aqueous ethanol vanadyl sulfate
Poskonin, VV
Badovskaya, LA
Povarova, LV
KHIMIYA GETEROTSIKLICHESKIKH SOEDINENII, 1998, (07): : 893 - 897
[16] Reactions of catalytic oxidation of furan and hydrofuran compounds. 7. Preparation of 2(5H)-furanone by oxidation of furfural with hydrogen peroxide and some its conversions in aqueous solutions
Badovskaya, LA
Latashko, KA
Poskonin, VV
Grunskaya, EP
Tjukhteneva, ZL
Rudakova, SG
Pestunova, SA
Sarkisyan, AV
KHIMIYA GETEROTSIKLICHESKIKH SOEDINENII, 2002, (09): : 1194 - 1203
[17] Catalytic oxidation of furan and hydrofuran compounds .1. General regularities of oxidation of furan in the system hydrogen peroxide-vanadium(IV) compound in relation to nature of solvent and catalyst
Poskonin, VV
Povarova, LV
Badovskaya, LA
KHIMIYA GETEROTSIKLICHESKIKH SOEDINENII, 1996, (05): : 633 - 638
[18] Catalytic oxidation of furan and hydrofuran compounds. 3. Synthesis of 2,5-diethoxy-2,5-dihydrofuran in the furan-hydrogen peroxide-aqueous ethanol-vanadyl sulfate system
Poskonin V.V.
Badovskaya L.A.
Povarova L.V.
Chemistry of Heterocyclic Compounds, 1998, 34 (7) : 771 - 774
[19] Catalytic oxidation of furan and hydrofuran ompounds. 2. Oxidation of furfural in the system hydrogen peroxide vanadyl sulfate sodium acetate
Poskonin, VV
Badovskaya, LA
KHIMIYA GETEROTSIKLICHESKIKH SOEDINENII, 1998, (06): : 742 - 747
[20] REACTIONS OF FURAN COMPOUNDS .5. FORMATION OF FURAN FROM FURFURALDEHYDE BY THE ACTION OF NICKEL OR COBALT CATALYSTS - IMPORTANCE OF ADDED HYDROGEN
WILSON, CL
JOURNAL OF THE CHEMICAL SOCIETY, 1945, (JAN-): : 61 - 63

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