Synthesis and crystal structure of the π copper(I) cyanide complex with N,N′-diallyl thiocarbamide 2CuCN · (C3H5NH)2CS

被引：0
作者：
A. A. Vakulka
Ya. E. Filinchuk
M. G. Mys’kiv
机构：
[1] Franko State University,
[2] University of Geneva,undefined
来源：
Russian Journal of Coordination Chemistry | 2007年 / 33卷
关键词：
Coordination Chemistry; Bipy; Cyano Group; Diallyl; Allyl Amine;
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摘要：
Crystals of the π copper(I) cyanide complex with N,N′-diallyl thiocarbamide, 2CuCN · (C3H5NH)2CS (I), are synthesized from an aqueous-methanol solution of potassium nitroprusside, diallyl thiocarbamide on a copper electrode using the method of alternating-current electrochemical synthesis. The crystals are monoclinic: space group P21/n, a = 6.9440(5) Å, b = 13.760(1)) Å, c = 12.733(1) Å, β = 97.280(9)°, V = 1206.8(2) Å3, Z = 4, R = 0.0361, Rw = 0.0362 for 2836 independent reflections with F ≥ 4σ(F). A unique polymeric structure is built due to the Cu(I)-(C=C) π bond and the bridging function of the thioamide S atom of the ligand molecule and one of the two independent cyano groups.
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页码：809 / 814
页数：5
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