Synthesis of 1-alkoxy-3-methyl-1-triazene 2-oxides and 3, 3´-methylene-bis(1-alkoxy-3-methyl-1-triazene 2-oxides)

被引:0
|
作者
G. A. Smirnov
P. B. Gordeev
S. V. Nikitin
G. V. Pokhvisneva
T. V. Ternikova
O. A. Luk’yanov
机构
[1] Russian Academy of Sciences,N. D. Zelinsky Institute of Organic Chemistry
来源
Russian Chemical Bulletin | 2015年 / 64卷
关键词
alkylation; methylenation; 3, 3-methylene-bis(1-alkoxy-3-methyl-1-triazene 2-oxides); salts of 1-alkoxy-3-methyl-1-triazene 2-oxides; bromination;
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学科分类号
摘要
A method for the synthesis of 1-alkoxy-3-methyl-1-triazene 2-oxides and their salts with alkali metals was developed. 3, 3´-Methylene-bis(1-alkoxy-3-methyl-1-triazene 2-oxides) were obtained for the first time. Some properties of the synthesized compounds were studied. These compounds can be of interest as new NO and HNO donors in living organisms.
引用
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页码:2712 / 2717
页数:5
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