Solvent Effect on the Activation Volume of the Diels-Alder Reaction Between Tetracyanoethylene and trans,trans-1,4-Diphenyl-1,3-butadiene

被引：0
作者：
V. D. Kiselev
M. S. Shikhaab
G. G. Iskhakova
A. I. Konovalov
机构：
[1] Kazan State University,Butlerov Research Institute of Chemistry
来源：
Russian Journal of General Chemistry | 2002年 / 72卷
关键词：
Hydrostatic Pressure; Reaction Volume; Solvent Effect; Activation Volume; Butadiene;
D O I：
暂无
中图分类号：
学科分类号：
摘要：
The effect of increased hydrostatic pressure on the rate of the Diels-Alder reaction of tetracyanoethylene with trans,trans-1,4-diphenyl-1,3-butadiene at 25°C was studied to estimate the reaction volume and to show that it considerably varies with π-donor properties of the medium.
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页码：98 / 104
页数：6
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