The 500 °C Isothermal Section of the Mn-Si-Sn Ternary System

被引：0
作者：
Haoping Peng
Lei Zhai
Shuai Jiang
Ze Zhu
Ya Liu
Xuping Su
机构：
[1] Changzhou University,Key Laboratory of Materials Surface Science and Technology of Jiangsu Province
[2] Changzhou University,Jiangsu Key Laboratory of Oil and Gas Storage and Transportation Technology
[3] Changzhou University,Jiangsu Collaborative Innovation Center of Photovoltaic Science and Engineering
来源：
Journal of Phase Equilibria and Diffusion | 2020年 / 41卷
关键词：
intermetallics; Mn-Si-Sn; phase equilibria;
D O I：
暂无
中图分类号：
学科分类号：
摘要：
Mn and Si are common elements in steel and have an important influence on the performance of steel. To analyze the intermetallic compounds formed in tin-base solder welding process, the Mn-Si-Sn alloys were prepared and annealed at 500 °C for 30 days. The phase equilibria in the Mn-Si-Sn system at 500 °C were studied by electron microscopy equipped with energy-dispersive spectrometry and x-ray diffraction. 12 three-phase regions were well determined in the Mn-Si-Sn system at 500 °C, and no ternary compound was found. The binary compound Mn5Si2, which is controversial in the literature, was not observed in the present study. Mn2−xSn (Mn1.8Sn) and Mn3Sn2 phases were detected by XRD rather than the Mn2Sn phase in this work. The solubility of Si in Mn3Sn, Mn2−xSn, Mn3Sn2, and MnSn2 was measured to be 0.7, 1.2, 1.2, and 0.4 at.%, respectively. And the Sn solubility in R-Mn6Si, υ-Mn9Si2, Mn3Si, MnSi, Mn11Si19 at 500 °C is about 0.9, 0.5, 0.3, 0.3 and 0.2 at.%, respectively.
引用
收藏
页码：835 / 845
页数：10
相关论文
共 111 条
[1]  
Chen J(2008)Effects of Sn Addition on Microstructure and Mechanical Properties of Mg-Zn-Al Alloys J. Alloys Compd. 461 209-215
[2]  
Chen Z(2010)Effect of Tin on the Corrosion Behavior of Low-Alloy Steel in an Acid Chloride Solution Corros. Sci. 52 14-20
[3]  
Yan H(2012)The Role of Chloride Ion on the Atmospheric Corrosion of Steel and Corrosion Resistance of Sn-Bearing Steel Corros. Sci. 62 34-41
[4]  
Zhang F(2010)Microstructural Characteristics of Lap Joint Between Magnesium Alloy and Mild Steel with and Without the Addition of Sn Element Mater. Lett. 64 89-92
[5]  
Liao K(2014)Influence of Minor Alloying Elements on Selective Oxidation and Reactive Wetting of CMnSi TRIP Steel During Hot-Dip Galvanizing Metall. Mater. Trans. A 45 4484-4498
[6]  
Nam ND(2012)Selective Oxidation of TWIP Steel During Continuous Annealing Steel Res. Int. 83 391-397
[7]  
Kim MJ(2014)The Influence of the Dew Point on the Wettability of Twinning-Induced-Plasticity Steels by Liquid Zn-0.23 wt% Al Corros. Sci. 85 364-371
[8]  
Jang YW(2006)Influence of H2-N2 Atmosphere Composition and Annealing Duration on the Selective Surface Oxidation of Low-Carbon Steels Corros. Sci. 48 980-993
[9]  
Kim JG(2012)Al-Mn-Si (Aluminum-Manganese-Silicon) Journal of Phase Equilibria and Diffusion 33 140-142
[10]  
Kamimura T(2015)Phase Equilibria of the Cu-Si-Sn System at 700 and 500 °C J. Phase Equilib. Diffus. 36 493-502
12345678910