Synthesis, crystal structure and spectroscopic characterization of mono- and tetra-nuclear molybdenum(VI) complexes with 2-mercaptopyridine N-oxide: (n-Bu4N)2[MoO2(PT)2·Mo4O8(μ-O)2(μ3-O)2(PT)2]

被引：0

作者：

Hong Liang

Zhen-Feng Chen

Rui-Xiang Hu

Qing Yu

Zhong-Yuan Zhou

Xiang-Ge Zhou

机构：

[1] Guangxi Normal University,Department of Chemistry

[2] Chinese Academy of Sciences,Institute of Organic Chemistry

来源：

Transition Metal Chemistry | 2002年 / 27卷

关键词：

Physical Chemistry; Crystal Structure; Inorganic Chemistry; Absorption Band; Molybdenum;

D O I：

暂无

中图分类号：

学科分类号：

摘要：

(n-Bu4N)4[Mo8O26] reacts with the Na salt of 2-mercaptopyridine N-oxide (NaPT) in MeCN to give the complex (n-Bu4N)2[MoO2(PT)2·Mo4O8(μ-O)2(μ3-O)2(PT)2] (1) which contains two metal centres: one being mononuclear molybdenum chelating to two PT ligands, and the other a tetranuclear oxomolybdenum cluster with two PT ligands at the terminal point. The i.r. spectrum of the title complex exhibits absorption bands at 911.5 and 881.9 cm−1, characteristic of the [cis-MoO2]2+ fragment.

引用

页码：102 / 104

页数：2

共 73 条

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