Synthesis and crystal structure of (H3O)2{(Na2(OH)CB[5])2[HV4O12]}Cl · 14H2O

被引：0
|
作者：
E. A. Kovalenko
D. Yu. Naumov
V. P. Fedin
机构：
[1] Russian Academy of Sciences,Nikolaev Institute of Inorganic Chemistry, Siberian Division
[2] Novosibirsk State University,undefined
来源：
Russian Journal of Coordination Chemistry | 2011年 / 37卷
关键词：
Coordination Chemistry; Chloride Anion; Sodium Atom; Sodium Vanadate; Cucurbituril;
D O I：
暂无
中图分类号：
学科分类号：
摘要：
The compound (H3O)2{(Na2(OH)CB[5])2[HV4O12]}Cl · 14H2O is synthesized by heating (120°C) of a mixture of sodium vanadate, cucurbit[5]uril (CB[5]), rubidium chloride, and water in a sealed ampule. According to the X-ray diffraction data, the binding of the [Na2(OH)]+ binuclear cation with CB[5] occurs due to the bidentate coordination of the oxygen atoms of the portals of cucurbit[5]uril to the sodium atoms. The tetranuclear vanadium complex [HV4O12]3− serves as a bridge, joining infinite chains {Na2(OH)CB[5]}∞+ in pairs.
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页码：137 / 142
页数：5
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