Extraction distribution of microamounts of strontium in the two-phase water-KCl-15-crown-5-nitrobenzene-potassium dicarbollylcobaltate system

被引：0

作者：

Vaňura P. ^{[1
]}

Makrlík E. ^{[2
]}

Selucký P. ^{[3
]}

机构：

[1] Prague Institute of Chemical Technology, 166 28 Prague 6

[2] Faculty of Applied Sciences, University of West Bohemia, 306 14 Pilsen

[3] Nuclear Research Institute

来源：

Journal of Radioanalytical and Nuclear Chemistry | 2006年 / 268卷 / 1期

关键词：

Potassium; Physical Chemistry; Inorganic Chemistry; Strontium; Organic Phase;

D O I：

10.1007/s10967-006-0143-4

中图分类号：

学科分类号：

摘要：

Extraction of microamounts of strontium by a nitrobenzene solution of potassium dicarbollylcobaltate (K+B-) in the presence of 15-crown-5 (15C5, L) has been investigated. The equilibrium data have been explained assuming that the complexes KL+, KL2+ and SrL22+ are extracted into the organic phase. The values of extraction and stability constants of the species in nitrobenzene saturated with water have been determined. © 2006 Akadémiai Kiadó.

引用

页码：159 / 162

页数：3

共 13 条

[1] Pedersen C.J., J. Am. Chem. Soc., 89, (1967)
[2] Kolthoff I.M., Anal. Chem., 51, (1979)
[3] Hawthorne M.F., Young D.C., Andrews T.D., Hove D.V., Pilling R.L., Pitts A.D., Reintjes M., Warren L.F., Wegner P.A., J. Am. Chem. Soc., 90, (1968)
[4] Makrlik E., Collect. Czech. Chem. Commun., 57, (1992)
[5] Iwachido T., Minami M., Sadakane A., Toei K., Chem. Lett., (1977)
[6] Vanura P., Rais J., Selucky P., Kyrs M., Collect. Czech. Chem. Commun., 44, (1979)
[7] Rais J., Collect. Czech. Chem. Commun., 36, (1971)
[8] Izatt R.M., Pawlak K., Bradshaw J.S., Bruening R.L., Chem. Rev., 91, (1991)
[9] Izatt R.M., Terry R.E., Haymore B.L., Hansen L.D., Dalley N.K., Avondet A.G., Christensen J.J., J. Am. Chem. Soc., 98, (1976)
[10] Valentova Z., Vanura P., Makrlik E., J. Radioanal. Nucl. Chem., 224, (1997)

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