DSC study of the kinetic parameters of the metastable phases formation during non-isothermal annealing of an Al–Si–Mg alloy

被引:0
作者
Mourad Ibrahim Daoudi
Abdelhafid Triki
Abdelkrim Redjaimia
机构
[1] University of Guelma Algeria and LM2S Laboratory,Physics Department
[2] University of Annaba and LM2S Laboratory,Physics Department
[3] Institut Jean Lamour,undefined
[4] Ecole des Mines de Nancy,undefined
来源
Journal of Thermal Analysis and Calorimetry | 2011年 / 104卷
关键词
Al–Si–Mg alloy; DSC; Kinetic parameters; Isoconversional methods;
D O I
暂无
中图分类号
学科分类号
摘要
Kinetics of β″ and β′ precipitations in an AlSiMg have been studied under non-isothermal conditions using differential scanning calorimetry (DSC) technique. The variation of the activation energy as a function of transformed fraction is determined using two isoconversional methods of Kissinger–Akahira–Sunose (KAS) and Friedman. The results obtained using the two methods show a change in the activation energy for both metastable phases precipitations as a function of transformed fraction. The results obtained from KAS method as compared with those obtained from Friedman method, show some major disagreements between the two methods. The growth exponent, determined by Ozawa method, decreases as a function of temperature for both phases.
引用
收藏
页码:627 / 633
页数:6
相关论文
共 117 条
  • [21] Andersen SJ(2009)Degradation behavior and kinetic study of ABS polymer J Therm Anal Calorim 95 273-476
  • [22] Zandbergen HW(2009)Kinetics of thermal degradation of polymers. Complementary use of isoconversional and model-fitting methods J Therm Anal Calorim 98 469-13
  • [23] Jansen J(2009)DSC studies on the curing of chitosan-alanine using glutaraldehyde as crosslinker J Therm Anal Calorim 97 507-42
  • [24] Træholt C(2009)Non-isothermal crystallization kinetics of some basaltic glass-ceramics containing CaF J Therm Anal Calorim 95 37-166
  • [25] Tundal U(2009) as nucleation agent J Therm Anal Calorim 95 161-573
  • [26] Reiso O(2009)Studies on crystallization kinetics of tellurite 20Li J Therm Anal Calorim 96 567-362
  • [27] Miao WF(2010)O–80TeO J Therm Anal Calorim 99 357-4631
  • [28] Laughlin DE(2006) glass Acta Mater 54 4621-202
  • [29] Dutta I(1971)Thermal decomposition kinetics of some aromatic azomonoethers. Part III. Non-isothermal study of 4-[(4-chlorobenzyl)oxy]-4′-chloroazobenzene in dynamic air atmosphere J Nucl Mater 38 197-361
  • [30] Allen SM(1973)Isoconversional kinetic analysis of resol-clay nanocomposites Neue Huette 18 356-1815