Reactivity of metal-containing monomersThermal transformations of cobalt(II) maleate

被引：0
|
作者：
A. S. Rosenberg
E. I. Aleksandrova
N. P. Ivleva
G. I. Dzhardimalieva
A. V. Raevskii
O. I. Kolesova
I. E. Uflyand
A. D. Pomogailo
机构：
[1] Russian Academy of Sciences,Institute of Chemical Physics in Chermogolovka
来源：
Russian Chemical Bulletin | 1998年 / 47卷
关键词：
metal carboxylates; thermolysis; solid-phase polymerization; nano-sized particles; stabilization;
D O I：
暂无
中图分类号：
学科分类号：
摘要：
Thermal conversion of cobalt(II) maleate, CoC4H2O42H2O, (1) at 340–370 °C was studied. The composition of the products of pyrolysis was determined. The major solid-phase product of decomposition consists of nano-sized particles of CoO (sizes vary within narrow limits) stabilized by the polymeric matrix. Thermal conversions of CoII maleate involve dehydration, polymerization of dehydrated monomers, and decarboxylation of the resulting polymer.
引用
收藏
页码：259 / 264
页数：5
相关论文
共 20 条
  • [1] Reactivity of metal-containing monomers - 48. Thermal transformations of cobalt(II) maleate
    Rosenberg, AS
    Aleksandrova, EI
    Ivleva, NP
    Dzhardimalieva, GI
    Raevskii, AV
    Kolesova, OI
    Uflyand, IE
    Pomogailo, AD
    RUSSIAN CHEMICAL BULLETIN, 1998, 47 (02) : 259 - 264
  • [2] METAL-CONTAINING NANOCOMPOSITES BASED ON THE SALTS OF SATURATED COBALT(II) MONOCARBOXYL ACIDS
    Semenov, S. A.
    Pronin, A. S.
    Drobot, D. V.
    Dzhardimalieva, G. I.
    Popenko, V. I.
    NANOTECHNOLOGIES IN RUSSIA, 2019, 14 (11-12): : 536 - 542
  • [3] Synthesis and Thermal Transformations of Nickel(II) Salts of Saturated Monocarboxylic Acid-Precursors of Metal-Containing Nanocomposites
    Saprykin, R., V
    Semenov, S. A.
    Drobot, D., V
    Volchkova, E. V.
    Dzhardimalieva, G., I
    Ivanova, A. I.
    Golovanov, A. B.
    Popenko, V., I
    NANOBIOTECHNOLOGY REPORTS, 2022, 17 (03) : 345 - 355
  • [4] Reactivity of metal-containing monomers 71. Synthesis of nanosized quasicrystals and related metallopolymer composites
    S. M. Aldoshin
    G. I. Dzhardimalieva
    A. D. Pomogailo
    Yu. A. Abuzin
    Russian Chemical Bulletin, 2011, 60 : 1871 - 1879
  • [5] Reactivity of metal-containing monomers 71. Synthesis of nanosized quasicrystals and related metallopolymer composites
    Aldoshin, S. M.
    Dzhardimalieva, G. I.
    Pomogailo, A. D.
    Abuzin, Yu. A.
    RUSSIAN CHEMICAL BULLETIN, 2011, 60 (09) : 1871 - 1879
  • [6] Synthesis and Thermal Conversions of Unsaturated Nickel(II) Monocarboxylates—Precursors of Metal-Containing Nanocomposites
    A. S. Pronin
    S. A. Semenov
    D. V. Drobot
    E. V. Volchkova
    G. I. Dzhardimalieva
    Russian Journal of Inorganic Chemistry, 2020, 65 : 1173 - 1185
  • [7] Synthesis and Thermal Conversions of Unsaturated Nickel(II) Monocarboxylates-Precursors of Metal-Containing Nanocomposites
    Pronin, A. S.
    Semenov, S. A.
    Drobot, D. V.
    Volchkova, E. V.
    Dzhardimalieva, G. I.
    RUSSIAN JOURNAL OF INORGANIC CHEMISTRY, 2020, 65 (08) : 1173 - 1185
  • [8] Synthesis and reactivity of metal-containing monomers 74. Azomethine copper complexes as modifying agents of epoxy matrices
    Komarov, B. A.
    Kapasharov, A. T.
    Dzhavadyan, E. A.
    Lesnichaya, V. A.
    Dzhardimalieva, G. I.
    Burlov, A. S.
    Uraev, A. I.
    Mashchenko, S. A.
    Garnovskii, D. A.
    Pomogailo, A. D.
    RUSSIAN CHEMICAL BULLETIN, 2015, 64 (04) : 936 - 942
  • [9] Refractory Metal-Containing Polymers and Nanocomposites: Preparation and Properties
    Dzhardimalieva, Gulzhian I.
    Pomogailo, Svetlana I.
    Golubeva, Nina D.
    Pomogailo, Anatolii D.
    MACROMOLECULAR COMPLEXES, 2011, 304 : 101 - 108
  • [10] New Example of Metal-Containing Monomers for Frontal Polymerization
    Uflyand, Igor E.
    Zhinzhilo, Vladimir A.
    Dzhardimalieva, Gulzhian, I
    CHEMISTRYSELECT, 2019, 4 (07): : 2105 - 2108
12