Synthesis, crystal structure, and properties of new actinide(VI) arsenates (H3O)[(AnO2)(AsO4)]·3H2O (An = U, Np, Pu)

被引：4
|
作者：
Ivanova A.G. [1 ,2 ]
Budantseva N.A. [1 ]
Fedoseev A.M. [1 ]
机构：
[1] Frumkin Institute of Physical Chemistry and Electrochemistry, Russian Academy of Sciences, Leninskii pr. 31, korp. 4, Moscow
[2] Federal Research Center for Crystallography and Photonics, Russian Academy of Sciences, Leninskii pr. 59, Moscow
来源：
Radiochemistry | 2017年 / 59卷 / 2期
关键词：
absorption spectra; arsenate ion; crystal structure; hydrothermal synthesis; neptunium; plutonium; uranium;
D O I：
10.1134/S1066362217020035
中图分类号：
学科分类号：
摘要：
Previously unknown arsenates of hexavalent U, Np, and Pu, (H3O)[(UO2)(AsO4)]·3H2O (I), (H3O)· [(NpO2)(AsO4)]·3H2O (II), and (H3O)[(PuO2)(AsO4)]·3H2O (III), were synthesized under hydrothermal conditions. The crystal structure of the compounds was determined, and their absorption spectra were measured. The compounds crystallize in tetragonal space group P4/nmm. © 2017, Pleiades Publishing, Inc.
引用
收藏
页码：119 / 123
页数：4
相关论文
共 50 条
  • [31] Synthesis and structure of a new hybrid vanadium arsenate: [VO2(phen)]2(H2AsO4)⋅H3O
    Shou-Tian Zheng
    Jie Zhang
    Guo-Yu Yang
    Journal of Chemical Crystallography, 2005, 35 : 269 - 273
  • [32] AGCO3H2(ASO4)3 AND AGZN3H2(ASO4)3 - PREPARATION AND CRYSTAL-STRUCTURE - ANOTHER NEW STRUCTURE TYPE OF AN ARSENATE
    KELLER, P
    RIFFEL, H
    ZETTLER, F
    HESS, H
    ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 1981, 474 (03): : 123 - 134
  • [33] Interaction of U(VI), Np(VI), Pu(VI), and Np(V) with benzenetricarboxylic acids: Complexation in aqueous solutions, synthesis, and crystal structure of uranyl complexes [UO2(H2O)2{C6H3(COO)2(COOH)}]2·2H2O and [(UO2)3(H2O)4{C6H3(COO)3}2]
    A. B. Yusov
    M. N. Sokolova
    M. S. Grigor’ev
    A. M. Fedoseev
    N. A. Budantseva
    P. Moisy
    Radiochemistry, 2012, 54 (2) : 105 - 114
  • [34] The crystal structure of K2[VO(C3H2O4)2H2O]•3H2O
    Filippova, IG
    Kiosse, GA
    RUSSIAN JOURNAL OF COORDINATION CHEMISTRY, 2000, 26 (09) : 625 - 628
  • [35] Rollandite, Cu3 (AsO4)2•4H2O, a new mineral:: its description and crystal structure
    Sarp, H
    Cerny, R
    EUROPEAN JOURNAL OF MINERALOGY, 2000, 12 (05) : 1045 - 1050
  • [36] CRYSTAL-STRUCTURE OF ZNHPO4.H2O=(H3O)ZNPO4
    SANDOMIRSKII, PA
    KLIENTOVA, GP
    SIMONOV, MA
    BELOV, NV
    DOKLADY AKADEMII NAUK SSSR, 1977, 236 (03): : 597 - 600
  • [37] CRYSTAL STRUCTURE OF CALCIUM FUMARATE, TRIHYDRATE CAC4H2O4, 3H2O
    GUPTA, MP
    SAHU, BN
    INDIAN JOURNAL OF PHYSICS AND PROCEEDINGS OF THE INDIAN ASSOCIATION FOR THE CULTIVATION OF SCIENCE, 1969, 43 (08): : 487 - &
  • [38] Agardite-(Ce) -: CeCu6(AsO4)3(OH)6*3H2O
    Mandarino, JA
    CANADIAN MINERALOGIST, 2004, 42 : 1901 - 1901
  • [39] CRYSTAL-STRUCTURE OF AGCU3CU(ASO4)3 AND ITS STRUCTURAL RELATIONS TO AGCO3H2(ASO4)3 AND AGZN3H2 (ASO4)3
    RIFFEL, H
    KELLER, P
    HESS, H
    ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 1985, 530 (11): : 60 - 68
  • [40] Crystal structure of oxonium 4,4′-bipyridinium chromium-molybdate(VI) trihydrate, [H3O][C10H10N2][CrMo6H6O24] • 3H2O
    Wu, Li-Zhou
    ZEITSCHRIFT FUR KRISTALLOGRAPHIE-NEW CRYSTAL STRUCTURES, 2011, 226 (02): : 205 - 206
12345