Cobalt-chitosan: Magnetic and biodegradable heterogeneous catalyst for selective aerobic oxidation of alkyl arenes and alcohols

被引:12
作者
Shaabani, Ahmad [1 ]
Boroujeni, Mahmoud Borjian [1 ]
Sangachin, Mona Hamidzad [1 ]
机构
[1] Shahid Beheshti Univ, GC, Fac Chem, Tehran, Iran
关键词
Cobalt; chitosan; heterogeneous catalyst; magnetism; aerobic oxidation; alkyl arene; SUPPORTED PALLADIUM CATALYST; SECONDARY ALCOHOLS; BENZYL ALCOHOL; EFFICIENT CATALYST; MOLECULAR-OXYGEN; COMPLEXES; DEHYDROGENATION; NANOPARTICLES; CYCLOHEXANE; CONVERSION;
D O I
10.1007/s12039-015-0959-y
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
A novel and biodegradable cobalt-chitosan as a magnetic heterogeneous catalyst was synthesized and characterized by XPS, FT-IR, EDX and TEM. Catalytic performance of cobalt- chitosan was tested by aerobic oxidation of alkyl arenes and alcohols. The results show that the catalyst exhibits excellent conversion for selective aerobic oxidation of various alkyl arenes, primary and secondary alcohols with air as the only oxidant. The catalyst can be easily separated by magnetic devices and reused for 5 runs without appreciable loss of activity.
引用
收藏
页码:1927 / 1935
页数:9
相关论文
共 53 条
  • [1] [Anonymous], 2004, Polym. Adv. Technol
  • [2] Nanoparticles as recyclable catalysts: The frontier between homogeneous and heterogeneous catalysis
    Astruc, D
    Lu, F
    Aranzaes, JR
    [J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2005, 44 (48) : 7852 - 7872
  • [3] Selective liquid phase oxidation using gold catalysts
    Bianchi, C
    Porta, F
    Prati, L
    Rossi, M
    [J]. TOPICS IN CATALYSIS, 2000, 13 (03) : 231 - 236
  • [4] Burke S.D., 1999, Handbook of Reagents for Organic Synthesis, Oxidizing and Reducing Agents
  • [5] Oxidation of glycerol using supported Pt, Pd and Au catalysts
    Carrettin, S
    McMorn, P
    Johnston, P
    Griffin, K
    Kiely, CJ
    Hutchings, GJ
    [J]. PHYSICAL CHEMISTRY CHEMICAL PHYSICS, 2003, 5 (06) : 1329 - 1336
  • [6] COLLINS JC, 1968, TETRAHEDRON LETT, P3363
  • [7] COREY EJ, 1975, TETRAHEDRON LETT, P2647
  • [8] COREY EJ, 1979, TETRAHEDRON LETT, P399
  • [9] Crespilho FN, 2006, INT J ELECTROCHEM SC, V1, P151
  • [10] Cobalt(III)-oxo cubane clusters as catalysts for oxidation of organic substrates
    Das, Birinchi Kumar
    Chakrabarty, Rajesh
    [J]. JOURNAL OF CHEMICAL SCIENCES, 2011, 123 (02) : 163 - 173