Two Chain Like B-Type-Anderson-Based Hybrids Synthesized in Choline Chloride/Urea Eutectic Mixture

被引：0
|
作者：
Shi-Ming Wang
Wei-Lin Chen
En-Bo Wang
机构：
[1] Northeast Normal University,Key Laboratory of Polyoxometalate Science of Ministry of Education, Department of Chemistry
来源：
Journal of Cluster Science | 2010年 / 21卷
关键词：
Eutectic mixture; Ionic liquids; B-Anderson type; Polyoxometalate;
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学科分类号：
摘要：
Two new chain like B-Anderson type polyoxomolybdates based hybrids {Na[(CH3)3N(CH2)2OH]2}[Al(OH)6Mo6O18]·2(NH2CONH2)·6H2O (1) and {Na[(CH3)3N(CH2)2OH]2}[Cr(OH)6Mo6O18]·2(NH2CONH2)·6H2O (2) were synthesized in choline chloride/urea eutectic mixture and characterized by element analysis, IR, UV–vis, TG, single-crystal X-ray analysis, and power X-ray diffraction. Through the linkage [Na(H2O)2(NH2CONH2)2]+, the [X(OH)6Mo6O18]3− (X = Al, Cr) units are arranged into a chain. Considering hydrogen bonding interactions between the chains, compound 1 and 2 are all well-arranged into 3-D supermolecular assembly. The structure is first obtained in the choline chloride/urea eutectic mixture.
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页码：133 / 145
页数：12
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