Hydrogenation of CO2 to formic acid in the presence of the Wilkinson complex

被引：0
作者：
N. N. Ezhova
N. V. Kolesnichenko
A. V. Bulygin
E. V. Slivinskii
S. Han
机构：
[1] Institute of High Temperatures,Russian Academy of Sciences
[2] . V. Topchiev Institute of Petrochemical Synthesis,Russian Academy of Sciences
[3] Korean Institute of Science and Technology,undefined
来源：
Russian Chemical Bulletin | 2002年 / 51卷
关键词：
hydrogenation; carbon dioxide; formic acid; Wilkinson complex; triphenylphosphine; P NMR spectroscopy;
D O I：
暂无
中图分类号：
学科分类号：
摘要：
Formic acid was synthesized in a high yield at room temperature in the presence of the Wilkinson complex and an excess of PPh3. The catalytic properties of the rhodium complex depend strongly on the reaction conditions. The mechanism of the rhodium catalyst deactivation was studied by the kinetic method and 31P NMR spectroscopy. The methods for the stabilization of the rhodium catalyst were found.
引用
收藏
页码：2165 / 2169
页数：4
相关论文
共 23 条
[1]  
Dewhirst K. C.(1968)undefined Inorg. Chem. 7 24-undefined
[2]  
Keim W.(1967)undefined Zh. Neorg. Khim. 12 1709-undefined
[3]  
Reilly C. A.(1993)undefined J. Org. Chem. 58 4187-undefined
[4]  
Varshavskii Y. S.(1967)undefined J. Inorg. Chem. 6 1709-undefined
[5]  
Cherkasov T. G.(1981)undefined Inorg. Chim. Acta 50 11-undefined
[6]  
Fukumoto Y.(1994)undefined J. Chem. Soc. (A), Dalton Trans. 19 2875-undefined
[7]  
Chatani N.(1972)undefined J. Am. Chem. Soc. 94 3240-undefined
[8]  
Murai S.(1977)undefined Inorg. Chim. Acta 24 49-undefined
[9]  
Varshavsky U. S.(undefined)undefined undefined undefined undefined-undefined
[10]  
Cherkasov T. G.(undefined)undefined undefined undefined undefined-undefined
123