Kinetics of Oxidation of 4-Oxoacids by N-Chlorosaccharin in Aqueous Acetic Acid Medium

被引：0
作者：
N. A. Mohamed Farook
机构：
[1] Khadir Mohideen College,Department of Chemistry
来源：
Journal of Solution Chemistry | 2007年 / 36卷
关键词：
Kinetics; Oxidation; 4-Oxoacids; NCSA; Reaction mechanism;
D O I：
暂无
中图分类号：
学科分类号：
摘要：
The oxidation kinetics of substituted and unsubstituted 4-oxoacids (S) by N-chlorosaccharin (NCSA) have been studied in aqueous acetic acid media. The reaction follows first-order kinetics in each of the 4-oxoacids, NCSA and H+. The effect of changes in the electronic nature of the substrate reveals that positive charge develops in the transition state. Based on the kinetic results and product analysis, a suitable mechanism has been proposed for the reaction of NCSA with 4-oxoacids.
引用
收藏
页码：345 / 356
页数：11
相关论文
共 50 条
  • [21] Kinetics and Mechanism of Oxidation of Benzaldehyde by Benzimidazolium Fluorochromate in Aqueous Acetic Acid Medium
    Mansoor, S. Sheik
    ASIAN JOURNAL OF CHEMISTRY, 2010, 22 (10) : 7591 - 7600
  • [22] Kinetics and mechanistic study of oxidation of α-amino acid leucine by TCICA in aqueous acetic acid medium
    Afsar, N.
    Manivannan, S.
    JOURNAL OF THE INDIAN CHEMICAL SOCIETY, 2020, 97 (05) : 749 - 752
  • [23] Kinetics and mechanism of oxidation of benzyl ethers by N-chloronicotinamide in aqueous acetic acid medium
    Mathiyalagan, N.
    Priya, V.
    Bosco, J. John
    JOURNAL OF THE INDIAN CHEMICAL SOCIETY, 2009, 86 (05) : 453 - 457
  • [24] Kinetics and the mechanism of oxidation of methoxy benzaldehydes by benzimidazolium fluorochromate in an aqueous acetic acid medium
    Malik, V. Saleem
    Asghar, Basim H.
    Mansoor, S. Sheik
    JOURNAL OF TAIBAH UNIVERSITY FOR SCIENCE, 2016, 10 (01): : 131 - 138
  • [25] KINETICS AND MECHANISM OF OXIDATION OF CHALCONES BY ISONICOTINIUM DICHROMATE (INDC) IN AQUEOUS ACETIC ACID MEDIUM
    Palaniappan, An.
    Raju, C.
    Srinivasan, S.
    OXIDATION COMMUNICATIONS, 2010, 33 (01): : 77 - 87
  • [26] Permanganate oxidation of azoxybenzenes in aqueous acetic acid medium
    Gopalakrishnan, M
    Uma, M
    Jayabharathi, J
    Thanikachalam, V
    OXIDATION COMMUNICATIONS, 2000, 23 (03): : 392 - 398
  • [27] Oxidation of benzyl ethers by N-bromoisonicotinamide in aqueous acetic acid medium: A Kinetics and Mechanistic Study
    Balasubramaniyan, M.
    Mathiyalagan, N.
    RESEARCH JOURNAL OF CHEMISTRY AND ENVIRONMENT, 2012, 16 (04): : 116 - 119
  • [28] Kinetics and mechanism of oxidation of camphor by trichloro isocyanuric acid in aqueous acetic acid-perchloric acid medium
    Rao, T. L. M. V. Subba
    Sundar, B. Syama
    Radrakrishnamurti, P. S.
    OXIDATION COMMUNICATIONS, 2008, 31 (02): : 335 - 339
  • [29] Kinetics and mechanism of oxidation of aromatic aldehydes by 1-chlorobenzimidazole in aqueous acetic acid medium
    Ramkumar, B
    AFINIDAD, 2003, 60 (505) : 257 - 261
  • [30] Kinetics and mechanism of oxidation of some heterocyclic aldehydes by benzimidazolium fluorochromate in aqueous acetic acid medium
    Malik, V. Saleent
    Vannamtithu, I.
    Shafi, S. Syed
    Mansoor, S. Sheik
    JOURNAL OF THE INDIAN CHEMICAL SOCIETY, 2016, 93 (12) : 1357 - 1364
12345