A frequency-dependent surfactant bridge model for the electrorheological behaviors of surfactant-activated suspensions

被引:0
作者
Young Dae Kim
Moo Sung Lee
机构
[1] Chonnam National University,Faculty of Applied Chemistry
来源
Korean Journal of Chemical Engineering | 2004年 / 21卷
关键词
Electrorheology; Surfactant Bridge Model; Suspension; Electric Field Frequency; Surfactant;
D O I
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中图分类号
学科分类号
摘要
In surfactant-activated electrorheological (ER) suspensions, the ER response shows linear ER behavior (Τ∞Eo2 at small surfactant concentrations and nonlinear ER behavior (Τ∞Eon,n>2) at large surfactant concentrations. A surfactant bridge model was proposed to explain the nonlinear ER behavior at large surfactant concentrations with some assumptions. The proposed model successfully predicted the qualitative nonlinear ER behavior of surfactant-activated ER suspensions at large surfactant concentrations. Here, the surfactant bridge model is expanded to predict the electric field frequency dependent ER behavior of surfactant-activated ER suspensions. The developed surfactant bridge model can predict both the linear ER behavior at small surfactant concentrations and the nonlinear ER behavior at large surfactant concentrations. Furthermore, this model can predict two different types of the electric field frequency dependent ER behaviors of surfactant-activated ER suspensions, which depend on the amount of surfactants.
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页码:567 / 574
页数:7
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  • [1] Block H.(1988)Electro-rheology J. Phys. D: Appl. Phys. 21 1661-1661
  • [2] Kelly J. P.(2001)Electrorheological Response of Particulate Suspensions and Emulsions in a Small-strain Shear Flow: Viscoelasticity and Yield Phenomena Korean J. Chem. Eng. 18 54-54
  • [3] Chin B. D.(2001)A Yield stress Scaling Function for Electrorheological Fluids Appl. Phys. Lett. 78 3806-3806
  • [4] Park O. O.(1984)Electric Fields in the Rheological Disperse System Rheol. Acta 23 636-636
  • [5] Choi H. J.(1989)Electrorheological Fluids as Colloidal Suspensions Adv. Coll. Int. Sci. 30 153-153
  • [6] Cho M. S.(1997)Studies on Model Electrorheological Fluids J. Phys. Chem. B 101 1961-1961
  • [7] Kim J. W.(1979)Dielectrophoretic Levitation of Spheres and Shells J. Electrostatics 6 207-207
  • [8] Kim C. A.(1989)Electrorheology IEEE Trans. Elect. Insul. 24 849-849
  • [9] Jhon M. S.(1996)Two Roles of Nonionic Surfactants on the Electrorheological Response J. Colloid Interface Sci 183 568-568
  • [10] Deinega Y. F.(2001)A surfactant Bridge Model for the Nonlinear Electrorheological Effects of Surfactant-Activated ER Suspensions J. Colloid Interface Sci. 236 225-225