In this paper, we introduce biorthogonal multiple vector-valued wavelets which are wavelets for vector fields. We proved that, like in the scalar and multiwavelet case, the existence of a pair of biorthogonal multiple vector-valued scaling functions guarantees the existence of a pair of biorthogonal multiple vector-valued wavelet functions. Finally, we investigate the construction of a class of compactly supported biorthogonal multiple vector-valued wavelets. © 2006 Korean Society for Computational & Applied Mathematics and Korean SIGCAM.